((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane

Base Information

Chemical Name:((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane
CAS No.:705284-34-0
Molecular Formula:C₁₈H₂₀OSi
Molecular Weight:280.442
Hs Code.:

Synonyms:((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane

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Chemical Property of ((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane

Chemical Property:

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Technology Process of ((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane

There total 2 articles about ((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-22-5
Isopropenyl acetate

: 57857-90-6,89417-14-1,116051-23-1,122673-93-2
(+/-)-trans-2-iodocyclopentanol

: diphenylmethylsilylimidazole

: 109667-02-9
(R)-2-cyclopentenyl acetate

: 705284-34-0
((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane

Guidance literature:: Isopropenyl acetate; (+/-)-trans-2-iodocyclopentanol; With Amano Lipase AH; In hexane; at 37 ℃; for 5h;

diphenylmethylsilylimidazole; In hexane; at 20 ℃; for 0.333333h;

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In hexane; for 4h; Heating;
DOI:10.1021/ja048808x

Reference yield:

: 285-67-6
Cyclopentene oxide

: 705284-34-0
((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 89.5 percent / CeCl₃*7H₂O; NaI / acetonitrile / 24 h / 20 °C

2.1: Amano Lipase AH / hexane / 5 h / 37 °C

2.2: hexane / 0.33 h / 20 °C

2.3: DBU / hexane / 4 h / Heating

With cerium(III) chloride; Amano Lipase AH; sodium iodide; In hexane; acetonitrile;
DOI:10.1021/ja048808x

Reference yield:

: 705284-34-0
((S)-Cyclopent-2-enyloxy)-methyl-diphenyl-silane

: 705284-36-2
Benzyl-((S)-2-cyclopent-2-enyl-ethyl)-amine

Guidance literature:: Multi-step reaction with 6 steps

1.1: Bu₄NF / tetrahydrofuran / 0.75 h

2.1: pyridine / 2 h / 20 °C

3.1: LDA; tert-butyldimethylsilyl chloride / tetrahydrofuran; hexane / 8 h / Heating

3.2: 175 mg / aq. HCl / tetrahydrofuran; hexane / 0.5 h / 0 °C

4.1: SOCl₂ / 1 h / 60 °C

5.1: 21 g / Et₃N; DMAP / tetrahydrofuran / 2 h / 0 °C

6.1: 99.8 percent / LiAlH₄ / tetrahydrofuran / 4 h / Heating

With pyridine; dmap; lithium aluminium tetrahydride; thionyl chloride; tetrabutyl ammonium fluoride; tert-butyldimethylsilyl chloride; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane;
DOI:10.1021/ja048808x