1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline

Base Information

• Chemical Name: 1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline
• CAS No.: 907590-97-0
• Molecular Formula: C₂₉H₄₀N₂Si
• Molecular Weight: 444.735
• Mol file: 907590-97-0.mol

Synonyms:1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline

Chemical Property of 1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline

There total 1 articles about 1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C29H41N2PSi + 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene (244187-81-3) → 1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline (907590-97-0) + 1,3-bis(2,6-diisopropylphenyl)-2-phosphanylidene-2,3-dihydro-1H-imidazole (1448792-72-0)

Guidance literature:

In benzene-d6; at 20 ℃;

DOI:10.1021/ja4072699

Reference yield: 100.0%

1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline (907590-97-0) + phenylacetylene (536-74-3) → C37H46N2Si (1034170-47-2)

Guidance literature:

In hexane; at 20 ℃; for 3h;

DOI:10.1002/anie.200704939

Reference yield: 100.0%

1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline (907590-97-0) + acetylene (74-86-2,25067-58-7) → C5H6(NC6H3(CH(CH3)2)2)2SiC2H2 (1034170-45-0)

Guidance literature:

In hexane; at 20 ℃; for 3h;

DOI:10.1002/anie.200704939

upstream raw materials:

1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene

Downstream raw materials:

(CH((C=CH₂)CMe)(N(2,6-(i-Pr)2C₆H₃))2)SiP₄

C₅₈H₈₀N₄P₄Si₂

(N(2,6-iPr₂-C₆H₃)(CH₃CCHCCH₃)N(2,6-iPr₂-C₆H₃)Si(H)O(B(C₆F₅)3)

N(2,6-iPr₂-C₆H₃)(CH₃CCHCCH₃)N(2,6-iPr₂-C₆H₃)Si(H)⁽¹⁸⁾O(B(C₆F₅)3)