tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane

Base Information

• Chemical Name: tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane
• CAS No.: 98468-96-3
• Molecular Formula: C₁₈H₁₂B₃N₃O₉
• Molecular Weight: 446.741
• Mol file: 98468-96-3.mol

Synonyms:tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane

Chemical Property of tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane

There total 1 articles about tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitrophenylboronic acid (24067-17-2) → tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane (98468-96-3)

Guidance literature:

With sulfuric acid; at 100 ℃; for 10h; under 0.5 Torr;

DOI:10.1021/ol2012007

Reference yield: 88.0%

4-(2-methoxyethyl)-2-methylpyridine (1309579-38-1) + tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane (98468-96-3) → 2-methyl-4-[2-(4-nitrophenyl)ethyl]pyridine (1309579-43-8)

Guidance literature:

With triphenyl phosphite; methanol; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In toluene; at 120 ℃; for 24h;

DOI:10.1021/ol2012007

Reference yield: 53.0%

tris(4-nitrophenyl)-1,3,5,2,4,6-trioxatriborinane (98468-96-3) + 6-(phenyl(piperidin-1-yl)methyl)benzo[d][1,3]dioxol-5-ol → C20H15NO5

Guidance literature:

With [RhCl((R,R)-ferrocenyl-tfb*)]₂; potassium hydroxide; In 1,4-dioxane; at 20 - 40 ℃; for 15h; enantioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.5b03277

upstream raw materials:

4-nitrophenylboronic acid

Downstream raw materials:

2-methyl-4-[2-(4-nitrophenyl)ethyl]pyridine

4-nitrobenzonitrile