m-methylbenzoyl bromide

Base Information

• Chemical Name: m-methylbenzoyl bromide
• CAS No.: 34557-05-6
• Molecular Formula: C₈H₇BrO
• Molecular Weight: 199.047
• Mol file: 34557-05-6.mol

Synonyms:m-methylbenzoyl bromide

Chemical Property of m-methylbenzoyl bromide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of m-methylbenzoyl bromide

There total 4 articles about m-methylbenzoyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

m-Toluic acid (99-04-7) → m-methylbenzoyl bromide (34557-05-6)

Guidance literature:

With ((tribromomethyl)sulfonyl)benzene; triphenylphosphine; In dichloromethane; at 20 ℃;

DOI:10.1002/cbdv.202100329

Reference yield:

m-tolyl aldehyde (620-23-5) → m-methylbenzoyl bromide (34557-05-6)

Guidance literature:

With Bromotrichloromethane; In tetrachloromethane; Heating; Irradiation;

DOI:10.1016/S0040-4020(01)98675-2

Reference yield:

sodium 3-methylbenzoate (17264-86-7) → m-methylbenzoyl bromide (34557-05-6)

Guidance literature:

With Oxalyl bromide; In benzene; for 2h; Heating;

upstream raw materials:

m-tolyl aldehyde

sodium 3-methylbenzoate

m-Toluic acid

Downstream raw materials:

1-methoxycarbonyl-3-methylbenzene

Refernces

• 1、 Kevill, Dennis N.,Knauss, Donald C.. "Nucleophilic Substitution at a Trigonal Carbon. Part 5. Substituent Effects in the Reactions of Aromatic Acyl Bromides with Methanol in Acetonitrile". . p. 307 - 312. Retrieved 2007/10/02.