(1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine

Base Information

Chemical Name:(1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine
CAS No.:1610353-67-7
Molecular Formula:C₂₀H₂₉NO₂SSi
Molecular Weight:375.607
Hs Code.:

Synonyms:(1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine

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Chemical Property of (1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine

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Technology Process of (1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine

There total 3 articles about (1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: N-(2-methylbenzylidene)-1,1-dimethylethanesulfonamide

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 1610353-67-7
(1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine

Guidance literature:: N-(2-methylbenzylidene)-1,1-dimethylethanesulfonamide; dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane; With copper(I) triflate benzene complex; (1R,2R)-N,N’-diethyl-1,2-diphenylethylenediamine; In 1,2-dimethoxyethane; at 30 ℃; for 0.166667h;

With 2.6-dimethylphenol; In 1,2-dimethoxyethane; at 30 ℃; for 2h; enantioselective reaction;
DOI:10.1021/ol501143c

Reference yield:

: 529-20-4
2-methylphenyl aldehyde

: 1610353-67-7
(1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine

Guidance literature:: Multi-step reaction with 3 steps

1.1: pyridinium p-toluenesulfonate / dichloromethane / Reflux

2.1: acetic acid; peracetic acid / dichloromethane / 3 h / 20 °C

3.1: (1R,2R)-N,N’-diethyl-1,2-diphenylethylenediamine; copper(I) triflate benzene complex / 1,2-dimethoxyethane / 0.17 h / 30 °C

3.2: 2 h / 30 °C

With peracetic acid; copper(I) triflate benzene complex; (1R,2R)-N,N’-diethyl-1,2-diphenylethylenediamine; pyridinium p-toluenesulfonate; acetic acid; In 1,2-dimethoxyethane; dichloromethane;
DOI:10.1021/ol501143c

Reference yield:

: 1431623-81-2
C₁₂H₁₇NOS

: 1610353-67-7
(1R)-N-(tert-butylsulfonyl)-α-(dimethylphenylsilyl)-2-methylbenzylamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: acetic acid; peracetic acid / dichloromethane / 3 h / 20 °C

2.1: (1R,2R)-N,N’-diethyl-1,2-diphenylethylenediamine; copper(I) triflate benzene complex / 1,2-dimethoxyethane / 0.17 h / 30 °C

2.2: 2 h / 30 °C

With peracetic acid; copper(I) triflate benzene complex; (1R,2R)-N,N’-diethyl-1,2-diphenylethylenediamine; acetic acid; In 1,2-dimethoxyethane; dichloromethane;
DOI:10.1021/ol501143c