(Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene

Base Information

• Chemical Name: (Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene
• CAS No.: 1019206-96-2
• Molecular Formula: C₂₁H₃₆O₃Si
• Molecular Weight: 364.601
• Mol file: 1019206-96-2.mol

Synonyms:(Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene

Chemical Property of (Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene

Chemical Property:

Purity/Quality:

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• Hazard Codes: 

MSDS Files:

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Technology Process of (Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene

There total 1 articles about (Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

[5-(bisphenylthiomethoxy)pentyloxy](tert-butyl)dimethylsilane (1019206-91-7) + benzoic acid ethyl ester (93-89-0,99341-95-4) → (E)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene + (Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene (1019206-96-2)

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; magnesium; triethyl phosphite; In tetrahydrofuran; at 25 ℃; for 3h;

DOI:10.1021/ja800140g

Reference yield: 70.0%

(Z)-2,2,3,3-tetramethyl-12-phenyl-4,10,13-trioxa-3-silapentadec-11-ene (1019206-96-2) → (Z)-5-(2-ethoxy-2-phenylvinyloxy)pentan-1-ol (1019207-07-8)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 0.333333h;

DOI:10.1021/ja800140g

upstream raw materials:

[5-(bisphenylthiomethoxy)pentyloxy](tert-butyl)dimethylsilane

benzoic acid ethyl ester

Downstream raw materials:

(Z)-5-(2-ethoxy-2-phenylvinyloxy)pentan-1-ol