(+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

Base Information

Chemical Name:(+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol
CAS No.:137503-32-3
Molecular Formula:C₂₄H₃₂O₂Si
Molecular Weight:380.602
Hs Code.:

Synonyms:(+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

Suppliers and Price of (+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

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Technology Process of (+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

There total 3 articles about (+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 137503-31-2
(+)-(1S,1'S,2'R)-1-(2'-hydroxymethylcyclopent-4'-enyl)ethan-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 137503-32-3
(+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

Guidance literature:: With 1H-imidazole; In dichloromethane; for 0.5h; Ambient temperature;
DOI:10.1039/P19910002385

Reference yield:

: 14737-02-1,25169-69-1,27848-89-1,131898-31-2
endo-7-methylbicyclo<3.2.0>hept-2-en-6-one

: 137503-32-3
(+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

Guidance literature:: Multi-step reaction with 2 steps

1: 1) O₂ (air), 2) lithium aluminum hydride / 1) water, dimethylformamide, 30 deg C, biosynthesis by Acinetobacter NCIMB 9871, 2) diethyl ether, 1 h

2: 69 percent / imidazole / CH₂Cl₂ / 0.5 h / Ambient temperature

With 1H-imidazole; lithium aluminium tetrahydride; oxygen; In dichloromethane;
DOI:10.1039/P19910002385

Reference yield:

: 14737-02-1
2-Methyl-bicyclo<3.2.0>hept-6-en-3-on

: 137503-32-3
(+)-(1S,1'S,2'R)-1-(2'-tert-butyldiphenylsilyloxymethylcyclopent-4'-enyl)ethanol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) phosphate buffer (pH 7.2), 2.) LiAlH₄ / 1.) Pseudomonas sp. NCIB 9872, 2.) Et₂O, 0.5 h

2: imidazole / CH₂Cl₂ / 0.5 h

With 1H-imidazole; lithium aluminium tetrahydride; phosphate buffer; In dichloromethane;
DOI:10.1039/c39900001438