δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene

Base Information

• Chemical Name: δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene
• CAS No.: 855718-60-4
• Molecular Formula: C₁₃H₁₈O
• Molecular Weight: 190.285
• Mol file: 855718-60-4.mol

Synonyms:δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene

Chemical Property of δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene

There total 1 articles about δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4-dimethylacetophenone. (89-74-7) + allylmagnesium bromide (1730-25-2) → δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene (855718-60-4)

Guidance literature:

With diethyl ether;

Reference yield: 63.0%

δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene (855718-60-4) → C13H18O2

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; for 16h;

DOI:10.1002/anie.202007350

Reference yield:

δ-oxy-δ-[2.4-dimethyl-phenyl-α-amylene (855718-60-4) → C14H18O4

Guidance literature:

Multi-step reaction with 2 steps

1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 16 h / 0 - 20 °C

2: C₂₅H₂₀AlCl₆NO₄; tetrabutylammomium bromide / butanone / 18 h / 45 °C / 7500.75 Torr / Autoclave

With C₂₅H₂₀AlCl₆NO₄; tetrabutylammomium bromide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; butanone;

DOI:10.1002/anie.202007350

upstream raw materials:

2,4-dimethylacetophenone.

allylmagnesium bromide

Downstream raw materials:

3-(2,4-dimethyl-phenyl)-3-hydroxy-butyric acid