(Et₄N)4[Mo₂Fe₆S₈(S-p-C₆H₄Cl)6(tetrachlorocatecholato)2]

Base Information

• Chemical Name: (Et₄N)4[Mo₂Fe₆S₈(S-p-C₆H₄Cl)6(tetrachlorocatecholato)2]
• CAS No.: 89345-89-1
• Molecular Formula: 4C₈H₂₀N*C₄₈H₂₄Cl₁₄Fe₆Mo₂O₄S₁₄
• Molecular Weight: 2657.96
• Mol file: 89345-89-1.mol

Synonyms:(Et₄N)4[Mo₂Fe₆S₈(S-p-C₆H₄Cl)6(tetrachlorocatecholato)2]

Chemical Property of (Et₄N)4[Mo₂Fe₆S₈(S-p-C₆H₄Cl)6(tetrachlorocatecholato)2]

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of (Et₄N)4[Mo₂Fe₆S₈(S-p-C₆H₄Cl)6(tetrachlorocatecholato)2]

There total 1 articles about (Et₄N)4[Mo₂Fe₆S₈(S-p-C₆H₄Cl)6(tetrachlorocatecholato)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4(C2H5)4N(1+)*{Fe6S8(C2H5S)6Mo2(Cl4C6O2)2}(4-)=((C2H5)4N)4{Fe6S8(C2H5S)6Mo2(Cl4C6O2)2} + p-Chlorothiophenol (106-54-7) + acetonitrile (75-05-8,26809-02-9) → (Et4N)4[Mo2Fe6S8(S-p-C6H4Cl)6(tetrachlorocatecholato)2] (89345-89-1)

Guidance literature:

In acetonitrile; byproducts: ethanethiol; under Ar, slurry of MoFe-complex in MeCN treated with soln. of ClC6H4SHin MeCN, stirred for 40 min at ambient temp. with periodic evacuation; concd., stored overnight at -20°C, solid collected, washed with Et2O/MeCN, dried; filtrates concd., Et2O added, crystd. overnight at room temp. and 24 h at -20°C, solid collected, washed with Et2O/MeCN; recrystd. from Et2O/MeCN; elem. anal;

DOI:10.1021/ja00321a019

Reference yield: 82.0%

(Et4N)4[Mo2Fe6S8(S-p-C6H4Cl)6(tetrachlorocatecholato)2] (89345-89-1) + tetraethylammoniumcyanide (13435-20-6) → (Et4N)3[MoFe3S4(S-p-C6H4Cl)3(tetrachlorocatecholato)(CN)] (89345-93-7)

Guidance literature:

In acetonitrile; under Ar, soln. of MoFe complex in MeCN treated with soln. of (Et4N)CN in MeCN; filtered, concd., dild. with ether, stored overnight at -20°C, solid collected, washed with ether/propionitrile and ether, dried, recrystd. from MeCN/ether; elem. anal.;

DOI:10.1021/ja00321a019

upstream raw materials:

p-Chlorothiophenol

acetonitrile

Downstream raw materials:

(Et₄N)3[MoFe₃S₄(S-p-C₆H₄Cl)3(tetrachlorocatecholato)(CN)]