1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate

Base Information

Chemical Name:1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate
CAS No.:357924-26-6
Molecular Formula:C₁₉H₃₀O₄
Molecular Weight:322.445
Hs Code.:

Synonyms:1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate

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Chemical Property of 1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate

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Technology Process of 1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate

There total 6 articles about 1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 358339-06-7
(1R,5S)-(+)-8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]octan-7-one

: 357924-26-6
1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate

Guidance literature:: Multi-step reaction with 6 steps

1.1: diisobutylaluminium hydride / toluene / 0.75 h / -70 - 20 °C

2.1: Ba(OH)2*8H₂O / 2 h / 140 °C

2.2: 92 percent / tetrahydrofuran; H₂O / 30 h / 20 °C

3.1: 81 percent / PPTS / toluene / 7 h / 110 °C

4.1: 88 percent / tributyltin hydride; ZnCl₂ / Pd(PPh₃)4 / 0.25 h / 25 °C

5.1: tetrahydrofuran / 0.25 h / -20 - 0 °C

6.1: Et₃N; DMAP / tetrahydrofuran / 24 h / Heating

With dmap; barium dihydroxide; tri-n-butyl-tin hydride; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; triethylamine; zinc(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; toluene;
DOI:10.1002/1099-0690(200106)2001:12<2293::AID-EJOC2293>3.0.CO;2-E

Reference yield:

: 357924-22-2
8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]octan-7-ol

: 357924-26-6
1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate

Guidance literature:: Multi-step reaction with 5 steps

1.1: Ba(OH)2*8H₂O / 2 h / 140 °C

1.2: 92 percent / tetrahydrofuran; H₂O / 30 h / 20 °C

2.1: 81 percent / PPTS / toluene / 7 h / 110 °C

3.1: 88 percent / tributyltin hydride; ZnCl₂ / Pd(PPh₃)4 / 0.25 h / 25 °C

4.1: tetrahydrofuran / 0.25 h / -20 - 0 °C

5.1: Et₃N; DMAP / tetrahydrofuran / 24 h / Heating

With dmap; barium dihydroxide; tri-n-butyl-tin hydride; pyridinium p-toluenesulfonate; triethylamine; zinc(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; toluene;
DOI:10.1002/1099-0690(200106)2001:12<2293::AID-EJOC2293>3.0.CO;2-E

Reference yield:

: 357924-23-3
1-(8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]oct-7-yl)acetone

: 357924-26-6
1-{2-[3-(acetyloxy)-2,2-methyl-6-methylenecyclohexyl]ethyl}-1-methylprop-2-enyl acetate

Guidance literature:: Multi-step reaction with 4 steps

1: 81 percent / PPTS / toluene / 7 h / 110 °C

2: 88 percent / tributyltin hydride; ZnCl₂ / Pd(PPh₃)4 / 0.25 h / 25 °C

3: tetrahydrofuran / 0.25 h / -20 - 0 °C

4: Et₃N; DMAP / tetrahydrofuran / 24 h / Heating

With dmap; tri-n-butyl-tin hydride; pyridinium p-toluenesulfonate; triethylamine; zinc(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; toluene;
DOI:10.1002/1099-0690(200106)2001:12<2293::AID-EJOC2293>3.0.CO;2-E