2,3,9,10,16,17-hexa-tret-butylphenoxy-23-(4-formylbenzoyloxymethyl)phthalocyanate Zn(II)

Base Information

• Chemical Name: 2,3,9,10,16,17-hexa-tret-butylphenoxy-23-(4-formylbenzoyloxymethyl)phthalocyanate Zn(II)
• CAS No.: 937740-87-9
• Molecular Formula: C₁₀₁H₉₄N₈O₉Zn
• Molecular Weight: 1629.3
• Mol file: 937740-87-9.mol

Synonyms:2,3,9,10,16,17-hexa-tret-butylphenoxy-23-(4-formylbenzoyloxymethyl)phthalocyanate Zn(II)

Chemical Property of 2,3,9,10,16,17-hexa-tret-butylphenoxy-23-(4-formylbenzoyloxymethyl)phthalocyanate Zn(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,9,10,16,17-hexa-tret-butylphenoxy-23-(4-formylbenzoyloxymethyl)phthalocyanate Zn(II)

There total 1 articles about 2,3,9,10,16,17-hexa-tret-butylphenoxy-23-(4-formylbenzoyloxymethyl)phthalocyanate Zn(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2,3,9,10,16,17-hexa-tret-butylphenoxy-23-hydroxymethylphthalocyanate Zn(II) dihydrate + 4-Carboxybenzaldehyde (619-66-9) → 2,3,9,10,16,17-hexa-tret-butylphenoxy-23-(4-formylbenzoyloxymethyl)phthalocyanate Zn(II) (937740-87-9)

Guidance literature:

With C₆H₁₁NCNC₆H₁₁; (CH₃)2NC₅H₄N; In tetrahydrofuran; byproducts: (C6H11NH)2CO; dissolution of HOOCC6H4CHO, (C6H11N)2C and Me2NC5H4N,in THF under Ar, stirring for 20 min at -20 °C, dropwise addn. of soln. of phthalocyanine in THF, stirring for 25 h at room temp.; filtration, removal of solvent, washing with water and methanol, chromy.on silica gel with hexane/THF 2:1, elem. anal.;

DOI:10.1021/ja068240n

upstream raw materials:

4-Carboxybenzaldehyde