D-glycero-L-gulo-Heptitol, 2,6-dideoxy-2,6-[[(phenylmethoxy)carbonyl]imino]-1,3,4,5-tetrakis-O-(phenylmethyl)-7-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-

Base Information

Chemical Name:D-glycero-L-gulo-Heptitol, 2,6-dideoxy-2,6-[[(phenylmethoxy)carbonyl]imino]-1,3,4,5-tetrakis-O-(phenylmethyl)-7-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-
CAS No.:104343-35-3
Molecular Formula:C₅₇H₆₃NO₁₆
Molecular Weight:1018.12
Hs Code.:
DSSTox Substance ID:DTXSID001099753

D-glycero-L-gulo-Heptitol, 2,6-dideoxy-2,6-[[(phenylmethoxy)carbonyl]imino]-1,3,4,5-tetrakis-O-(phenylmethyl)-7-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-

Synonyms:104343-35-3;D-glycero-L-gulo-Heptitol, 2,6-dideoxy-2,6-[[(phenylmethoxy)carbonyl]imino]-1,3,4,5-tetrakis-O-(phenylmethyl)-7-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-;DTXSID001099753

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Chemical Property of D-glycero-L-gulo-Heptitol, 2,6-dideoxy-2,6-[[(phenylmethoxy)carbonyl]imino]-1,3,4,5-tetrakis-O-(phenylmethyl)-7-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-

Chemical Property:

XLogP3:6.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:16
Rotatable Bond Count:28
Exact Mass:1017.41468492
Heavy Atom Count:74
Complexity:1700

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(O1)OCC2C(C(C(C(N2C(=O)OCC3=CC=CC=C3)COCC4=CC=CC=C4)OCC5=CC=CC=C5)OCC6=CC=CC=C6)OCC7=CC=CC=C7)OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of D-glycero-L-gulo-Heptitol, 2,6-dideoxy-2,6-[[(phenylmethoxy)carbonyl]imino]-1,3,4,5-tetrakis-O-(phenylmethyl)-7-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-

There total 3 articles about D-glycero-L-gulo-Heptitol, 2,6-dideoxy-2,6-[[(phenylmethoxy)carbonyl]imino]-1,3,4,5-tetrakis-O-(phenylmethyl)-7-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 104343-31-9
2,6-dideoxy-2,6-<<(phenylmethoxy)carbonyl>imino>-1,3,4,5-tetrakis-O-(phenylmethyl)-D-glycero-L-gulo-heptitol

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 104343-35-3
2,6-dideoxy-2,6-<<(phenylmethoxy)carbonyl>imino>-7-O-<2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl>-1,3,4,5-tetrakis-O-(phenylmethyl)-D-glycero-L-gulo-hepitol

Guidance literature:: With 4 A molecular sieve; mercury(II) cyanide; In nitromethane; toluene; at 60 ℃; for 3.5h;
DOI:10.1021/jo00230a012

Reference yield:

: 501-53-1,94274-21-2
benzyl chloroformate

: 104343-35-3
2,6-dideoxy-2,6-<<(phenylmethoxy)carbonyl>imino>-7-O-<2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl>-1,3,4,5-tetrakis-O-(phenylmethyl)-D-glycero-L-gulo-hepitol

Guidance literature:: Multi-step reaction with 3 steps

1: K₂CO₃ / tetrahydrofuran / 1 h / Ambient temperature

3: 79 percent / mercuric cyanide, 4A molecular sieves / toluene; nitromethane / 3.5 h / 60 °C

With 4 A molecular sieve; mercury(II) cyanide; potassium carbonate; In tetrahydrofuran; nitromethane; toluene;
DOI:10.1021/jo00230a012

Reference yield:

: 104343-30-8
1,2,6-trideoxy-6-<<(phenylmethoxy)carbonyl>amino>-3,4,5,7-tetrakis-O-(phenylmethyl)-D-gluco-hept-1-enitol

: 104343-35-3
2,6-dideoxy-2,6-<<(phenylmethoxy)carbonyl>imino>-7-O-<2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl>-1,3,4,5-tetrakis-O-(phenylmethyl)-D-glycero-L-gulo-hepitol

Guidance literature:: Multi-step reaction with 2 steps

2: 79 percent / mercuric cyanide, 4A molecular sieves / toluene; nitromethane / 3.5 h / 60 °C

With 4 A molecular sieve; mercury(II) cyanide; In nitromethane; toluene;
DOI:10.1021/jo00230a012