C₃₉H₂₄N₄NiO

Base Information

Chemical Name:C₃₉H₂₄N₄NiO
CAS No.:883148-61-6
Molecular Formula:C₃₉H₂₄N₄NiO
Molecular Weight:623.336
Hs Code.:

C<sub>39</sub>H<sub>24</sub>N<sub>4</sub>NiO

Synonyms:C₃₉H₂₄N₄NiO

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Chemical Property of C₃₉H₂₄N₄NiO

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Technology Process of C₃₉H₂₄N₄NiO

There total 2 articles about C₃₉H₂₄N₄NiO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 67108-97-8
(5,10,15-triphenylporphyrinato)nickel(II)

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 883148-61-6
5-formyl-10,15,20-triphenylporphyrinatonickel(II)

Guidance literature:: With trichlorophosphate; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; under Ar; freshly distd. POCl3 added dropwise to dry DMF at 0°C with stirring; warmed to room temp.; stirred for 30 min; heated to 50°C; Ni complex in dry 1,2-dichloroethane added dropwise over 45 min; stirred for 2 h; minitored by TLC; transferred to satd. NaOAc soln.; stirred overnight; org. layer sepd.; washed with deionized water; dried (Na2SO4); solvent evapd.; subjected tocolumn chromy. (silica gel, CHCl3-n-hexane 3:1); recrystd. from CHCl3-M eOH;
DOI:10.1039/b516989e

Reference yield: 20.0%

: 591-50-4
iodobenzene

: 883148-64-9
5-ethenyl-10,15,20-triphenylporphyrinatonickel(II)

: 883148-61-6
5-formyl-10,15,20-triphenylporphyrinatonickel(II)

: 883148-90-1
5-(1-phenylethenyl)-10,15,20-triphenylporphyrinatonickel(II)

: E-5-(2-phenylethenyl)-10,15,20-triphenylporphyrinatonickel(II)

Guidance literature:: With palladium diacetate; potassium carbonate; triphenylphosphine; In N,N-dimethyl-formamide; toluene; under Ar; Ni complex, Pd acetate, phosphine and K2CO3 dried under vac.; dry DMF, dry toluene and PhI (50-fold excess) added; degassed via freeze-pump-thaw cycles; sealed; heated to 105°C; stirred for 48 h; monitored by TLC; diluted with toluene; washed (H2O); org. layer collected; dried; purified by column chromy. (silica gel, CHCl3-n-hexane 1:9, CHCl3); second, third and fourth bands collected;
DOI:10.1039/b516989e