2-(SALICYLIDENEAMINO)PHENYL DISULFIDE

Base Information

• Chemical Name: 2-(SALICYLIDENEAMINO)PHENYL DISULFIDE
• CAS No.: 26907-82-4
• Molecular Formula: C26H20 N2 O2 S2
• Molecular Weight: 456.589
• Mol file: 26907-82-4.mol

Synonyms:o-Cresol, a,a'-[dithiobis(o-phenylenenitrilo)]di- (6CI,8CI);Bis[2-(2-hydroxybenzylideneamino)phenyl] disulfide; NSC 677549

Chemical Property of 2-(SALICYLIDENEAMINO)PHENYL DISULFIDE

Chemical Property:

• Vapor Pressure: 6.62E-19mmHg at 25°C
• Refractive Index: 1.654
• Boiling Point: 676.2°Cat760mmHg
• Flash Point: 362.8°C
• PSA: 108.80000
• Density: 1.23g/cm³
• LogP: 6.61380

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(SALICYLIDENEAMINO)PHENYL DISULFIDE

There total 5 articles about 2-(SALICYLIDENEAMINO)PHENYL DISULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

salicylaldehyde (90-02-8) + 2-Aminophenyl disulfide (1141-88-4) → 2,2'-((1E,1'E)-((disulfanediylbis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))diphenol (26907-82-4)

Guidance literature:

With acetic acid; In ethanol; for 1h; Reflux;

Reference yield: 94.0%

salicylaldehyde (90-02-8) + 2-Aminophenyl disulfide (1141-88-4) → N,N′-(1,1′-dithiobis(phenylene))bis(salicylideneimine) (26907-82-4)

Guidance literature:

In methanol; for 6h; Reflux;

DOI:10.1016/j.molliq.2015.12.094

Reference yield:

2-amino-benzenethiol (137-07-5) → 2,2'-((1E,1'E)-((disulfanediylbis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))diphenol (26907-82-4)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydrogen sulfate; periodic acid / water / 3 h / 20 °C

2: acetic acid / methanol

With sodium hydrogen sulfate; acetic acid; periodic acid; In methanol; water;

DOI:10.1016/j.bioorg.2020.103819

upstream raw materials:

salicylaldehyde

2-Aminophenyl disulfide

2-amino-benzenethiol

Downstream raw materials:

2-(2-hydroxyphenyl)benzothiazoline

2-(benzothiazol-2-yl)phenol

UO₂⁽²⁺⁾*(C₆H₃(O)HCHNC₆H₄S)2^(2-)*CH₃OH=UO₂(C₆H₃(O)HCHNC₆H₄S)2*CH₃OH

{(2-(2-mercaptophenyl)iminophenoxy)}zinc(II)