[(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)]

Base Information

• Chemical Name: [(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)]
• CAS No.: 811470-67-4
• Molecular Formula: C₃₈H₅₄Al₂N₂O₂
• Molecular Weight: 624.822
• Mol file: 811470-67-4.mol

Synonyms:[(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)]

Chemical Property of [(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)]

There total 1 articles about [(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4,4'-bipyridine (553-26-4) + diisobutyl-phenoxyaluminium → [(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)] (811470-67-4)

Guidance literature:

In dichloromethane; (N2); using Schlenk techniques; charging of round bottom flask with ((t-Bu)2Al(μ-OPh))2 and 4,4'-bipy; addn. of CH2Cl2 after 5 min; stirring for 18 h, cooling to -30°C for 20 days; removal of solvent, dissolving in degassed toluene, cooling to -30°C for 2 days, crystn.;

DOI:10.1039/b410662h

Reference yield:

[(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)] (811470-67-4) → 4,4'-bipyridine (553-26-4) + diisobutyl-phenoxyaluminium

Guidance literature:

In chloroform-d1; dissolving of (Al(t-Bu)2)(OPh))2(μ-bipy) in CDCl3; monitoring by NMR;

DOI:10.1039/b410662h

Reference yield:

[(Al(tert-butyl)2(OPh))2(μ-4,4'-bipyridine)] (811470-67-4) → [(Al(tert-butyl)2(OPh))2(μ-1,2-bis(4-pyridyl)ethylene)]

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: hexane

In hexane;

DOI:10.1039/b410662h

upstream raw materials:

4,4'-bipyridine

Downstream raw materials:

4,4'-bipyridine

[(Al(tert-butyl)2(OPh))2(μ-1,2-bis(4-pyridyl)ethane)]