p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester

Base Information

• Chemical Name: p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester
• CAS No.: 1035459-93-8
• Molecular Formula: C₂₆H₃₂O₄SSi
• Molecular Weight: 468.689
• Mol file: 1035459-93-8.mol

Synonyms:p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester

Chemical Property of p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester

Chemical Property:

Purity/Quality:

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Technology Process of p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester

There total 1 articles about p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

toluene-4-sulfonic acid 2-hydroxypropyl ester (32464-98-5,102044-99-5,103775-61-7,54619-31-7) + tert-butylchlorodiphenylsilane (58479-61-1) → p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester (1035459-93-8)

Guidance literature:

With silver nitrate; In N,N-dimethyl-formamide; for 3h; cooling;

DOI:10.1021/jo8002198

Reference yield: 89.0%

p-toluenesulfonic acid 2-(tert-butyldiphenylsilyloxy)-propyl ester (1035459-93-8) → 2-(tert-butyldiphenylsilyloxy)-propyl iodide (1035459-80-3)

Guidance literature:

With sodium iodide; In acetone; for 48h; Heating;

DOI:10.1021/jo8002198

upstream raw materials:

toluene-4-sulfonic acid 2-hydroxypropyl ester

tert-butylchlorodiphenylsilane

Downstream raw materials:

2-(tert-butyldiphenylsilyloxy)-propyl iodide