triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane

Base Information

Chemical Name:triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane
CAS No.:1359761-46-8
Molecular Formula:C₃₅H₅₈O₂Si₂
Molecular Weight:567.015
Hs Code.:

Synonyms:triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane

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Chemical Property of triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane

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Technology Process of triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane

There total 8 articles about triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 591-50-4
iodobenzene

: 1359761-25-3
triethyl (((1R,5S)-2-methyl-5-(prop-1-en-2-yl)-1-(prop-2-yn-1-yl)-3-(((triisopropylsilyl)-oxy)methyl)cyclohex-2-en-1-yl)oxy)silane

: 1359761-46-8
triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; hexane; at 50 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ol300058t

Reference yield:

: 1359761-41-3
(1R,5S)-2-methyl-5-(prop-1-en-2-yl)-1-(prop-2-yn-1-yl)-3-(((triisopropylsilyl)oxy)methyl)cyclohex-2-enol

: 1359761-46-8
triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole / N,N-dimethyl-formamide / 72 h / 20 °C

2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran; hexane / 24 h / 50 °C / Inert atmosphere

With 1H-imidazole; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;
DOI:10.1021/ol300058t

Reference yield:

: trans-(5R)-1-(hydroxymethyl)-5-isopropenyl-2-methylcyclohex-2-ene-1-ol

: 1359761-46-8
triethyl((1R,5S)-2-methyl-1-(3-phenylprop-2-ynyl)-5-(prop-1-en-2-yl)-3-((triisopropylsilyloxy)methyl)cyclohex-2-enyloxy)silane

Guidance literature:: Multi-step reaction with 5 steps

1: 1H-imidazole / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere

2: pyridinium chlorochromate / dichloromethane / 54 h / 23 °C

3: iodine; magnesium; mercury dichloride / diethyl ether; toluene / 20 h / 20 °C / Inert atmosphere

4: 1H-imidazole / N,N-dimethyl-formamide / 72 h / 20 °C

5: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran; hexane / 24 h / 50 °C / Inert atmosphere

With 1H-imidazole; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; iodine; magnesium; triethylamine; pyridinium chlorochromate; mercury dichloride; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ol300058t