(5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

Base Information

Chemical Name:(5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole
CAS No.:149774-48-1
Molecular Formula:C₂₇H₃₇NO₉
Molecular Weight:519.592
Hs Code.:

Synonyms:(5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

Suppliers and Price of (5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

There total 1 articles about (5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19877-13-5
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-enofuranose

: 50692-99-4
N-hydroxy-O²,O³;O⁴,O⁵-diisopropylidene-D-arabinonimidoyl chloride

: 149774-48-1
(5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

: (5S)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

Guidance literature:: With triethylamine; Yield given. Multistep reaction. Yields of byproduct given;
DOI:10.1016/S0040-4039(00)73574-X

Reference yield: 63.0%

: 149774-48-1
(5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

: 7-amino-3-O-benzyl-6,7-dideoxy-1,2:8,9:10,11-tri-O-isopropylidene-D-gluco/D-manno-α-D-gluco-undeco-1,4-furanose

: 149774-49-2
3-O-benzyl-6-deoxy-1,2:8,9:10,11-tri-O-isopropylidene-D-arabino-α-D-gluco-undecos-7-ulose-1,4-furanose

Guidance literature:: With hydrogen; boric acid; nickel; In methanol; water; for 7h;
DOI:10.1016/S0008-6215(99)00168-8

Reference yield:

: 149774-48-1
(5R)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-3-(1,2:3,4-di-O-isopropylidene-D-arabino-tetritol-1-yl)-4,5-dihydroisoxazole

: 149774-46-9
3-O-benzyl-6-deoxy-1,2:8,9:10,11-tri-O-isopropylidene-D-gluco-α-D-gluco-undecofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 63 percent / H₂; boric acid / Raney-nickel / methanol; H₂O / 7 h

2: NaBH₄ / ethanol; H₂O / 20 °C

With sodium tetrahydroborate; hydrogen; boric acid; nickel; In methanol; ethanol; water; 1: Hydrogenolysis / 2: Reduction;
DOI:10.1016/S0008-6215(99)00168-8