C₁₄⁽¹³⁾CH₂₂O₃

Base Information

Chemical Name:C₁₄⁽¹³⁾CH₂₂O₃
CAS No.:264279-46-1
Molecular Formula:C₁₅H₂₂O₃
Molecular Weight:251.327
Hs Code.:

C<sub>14</sub><sup>(13)</sup>CH<sub>22</sub>O<sub>3</sub>

Synonyms:C₁₄⁽¹³⁾CH₂₂O₃

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₁₄⁽¹³⁾CH₂₂O₃

Chemical Property:

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Technology Process of C₁₄⁽¹³⁾CH₂₂O₃

There total 12 articles about C₁₄⁽¹³⁾CH₂₂O₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 264279-45-0
C₁₄⁽¹³⁾CH₂₂O₂

: 264279-46-1
C₁₄⁽¹³⁾CH₂₂O₃

Guidance literature:: C₁₄⁽¹³⁾CH₂₂O₂; With lithium diisopropyl amide; In tetrahydrofuran; at -20 ℃; for 0.166667h;

With (+)-[(8,8-dichlorocamphoryl)sulfonyl]oxaziridine; In tetrahydrofuran; at -20 - 20 ℃; for 1.25h; Further stages.;
DOI:10.1002/(SICI)1099-0690(200003)2000:5<829::AID-EJOC829>3.0.CO;2-Z

Reference yield:

: 125095-55-8
[2-13C]-5-methyl-4-hexenenitrile

: 264279-46-1
C₁₄⁽¹³⁾CH₂₂O₃

Guidance literature:: Multi-step reaction with 12 steps

1.1: 82 percent / diethyl ether / 1 h / 0 °C

2.1: NaH / tetrahydrofuran / 0 - 20 °C

2.2: 51 percent / tetrahydrofuran / 2 h / 20 °C

3.1: 91 percent / conc. H₂SO₄ / nitromethane / 0.5 h / 0 °C

4.1: 80 percent / m-chloroperbenzoic acid / ethyl acetate / 0 - 20 °C

5.1: 1.92 g / LDA / tetrahydrofuran / -40 - 20 °C

6.1: 60 percent / pyridinium chlorochromate / CH₂Cl₂ / 0 - 20 °C

7.1: p-toluenesulfonic acid; trimethyl orthoformate

7.2: 92 percent / HCl / acetone

8.1: 51 percent / DIBAL-H / petroleum ether / 1 h / -60 - 20 °C

9.1: nBuLi / tetrahydrofuran / -20 °C

9.2: 88 percent / tetrahydrofuran / 1 h / 0 - 20 °C

10.1: 88 percent / DIBAL-H / petroleum ether / -80 - -20 °C

11.1: 98 percent / HCl / acetone; H₂O

12.1: LDA / tetrahydrofuran / 0.17 h / -20 °C

12.2: 68 percent / (+)-(8,8-dichlorocamphorsulfonyl)oxaziridine / tetrahydrofuran / 1.25 h / -20 - 20 °C

With hydrogenchloride; n-butyllithium; sulfuric acid; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium diisopropyl amide; trimethyl orthoformate; In tetrahydrofuran; diethyl ether; nitromethane; dichloromethane; water; ethyl acetate; acetone; Petroleum ether; 1.1: Methylation / 2.1: Metallation / 2.2: Condensation / 3.1: Cyclization / 4.1: Epoxidation / 5.1: Isomerization / 6.1: Oxidation / 7.1: Etherification / 7.2: Cyclization / 8.1: Reduction / 9.1: deprotonation / 9.2: Condensation / 10.1: Reduction / 11.1: deprotection / 12.1: Metallation / 12.2: Oxidation;
DOI:10.1002/(SICI)1099-0690(200003)2000:5<829::AID-EJOC829>3.0.CO;2-Z

Reference yield:

: C₇⁽¹³⁾CH₁₄O

: 264279-46-1
C₁₄⁽¹³⁾CH₂₂O₃

Guidance literature:: Multi-step reaction with 11 steps

1.1: NaH / tetrahydrofuran / 0 - 20 °C

1.2: 51 percent / tetrahydrofuran / 2 h / 20 °C

2.1: 91 percent / conc. H₂SO₄ / nitromethane / 0.5 h / 0 °C

3.1: 80 percent / m-chloroperbenzoic acid / ethyl acetate / 0 - 20 °C

4.1: 1.92 g / LDA / tetrahydrofuran / -40 - 20 °C

5.1: 60 percent / pyridinium chlorochromate / CH₂Cl₂ / 0 - 20 °C

6.1: p-toluenesulfonic acid; trimethyl orthoformate

6.2: 92 percent / HCl / acetone

7.1: 51 percent / DIBAL-H / petroleum ether / 1 h / -60 - 20 °C

8.1: nBuLi / tetrahydrofuran / -20 °C

8.2: 88 percent / tetrahydrofuran / 1 h / 0 - 20 °C

9.1: 88 percent / DIBAL-H / petroleum ether / -80 - -20 °C

10.1: 98 percent / HCl / acetone; H₂O

11.1: LDA / tetrahydrofuran / 0.17 h / -20 °C

11.2: 68 percent / (+)-(8,8-dichlorocamphorsulfonyl)oxaziridine / tetrahydrofuran / 1.25 h / -20 - 20 °C

With hydrogenchloride; n-butyllithium; sulfuric acid; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium diisopropyl amide; trimethyl orthoformate; In tetrahydrofuran; nitromethane; dichloromethane; water; ethyl acetate; acetone; Petroleum ether; 1.1: Metallation / 1.2: Condensation / 2.1: Cyclization / 3.1: Epoxidation / 4.1: Isomerization / 5.1: Oxidation / 6.1: Etherification / 6.2: Cyclization / 7.1: Reduction / 8.1: deprotonation / 8.2: Condensation / 9.1: Reduction / 10.1: deprotection / 11.1: Metallation / 11.2: Oxidation;
DOI:10.1002/(SICI)1099-0690(200003)2000:5<829::AID-EJOC829>3.0.CO;2-Z