4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside

Base Information

• Chemical Name: 4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside
• CAS No.: 1628073-58-4
• Molecular Formula: C₇₃H₇₂O₁₇
• Molecular Weight: 1221.36
• Mol file: 1628073-58-4.mol

Synonyms:4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside

Chemical Property of 4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside

There total 1 articles about 4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

4-methoxyphenyl (2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)-2-O-benzyl-α-L-fucopyranoside (1628073-57-3) + Ethyl-2,3,4-tri-O-benzoyl-1-thio-β-D-xylopyranosid (113727-05-2) → 4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside (1628073-58-4)

Guidance literature:

4-methoxyphenyl (2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)-2-O-benzyl-α-L-fucopyranoside; Ethyl-2,3,4-tri-O-benzoyl-1-thio-β-D-xylopyranosid; In dichloromethane; at 20 ℃; for 0.5h; Molecular sieve; Inert atmosphere;

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -25 ℃; for 1h; stereoselective reaction;

DOI:10.1055/s-0033-1341256

Reference yield: 66.0%

4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside (1628073-58-4) → 4-methoxyphenyl (β-D-xylopyranosyl)-(1→4)-[(α-D-rhamnopyranosyl)-(1→3)]-α-L-fucopyranoside (1628073-59-5)

Guidance literature:

4-methoxyphenyl (2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-(1→4)-[(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)]-2-O-benzyl-α-L-fucopyranoside; With palladium hydroxide, 20 wt% on carbon; hydrogen; In methanol; at 20 ℃; for 24h;

With sodium methylate; In methanol; at 20 ℃; for 10h;

DOI:10.1055/s-0033-1341256

upstream raw materials:

4-methoxyphenyl (2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1→3)-2-O-benzyl-α-L-fucopyranoside

Ethyl-2,3,4-tri-O-benzoyl-1-thio-β-D-xylopyranosid

Downstream raw materials:

4-methoxyphenyl (β-D-xylopyranosyl)-(1→4)-[(α-D-rhamnopyranosyl)-(1→3)]-α-L-fucopyranoside