(2Z)-3-(Dimethylphenylsilyl)-2-octenal

Base Information

Chemical Name:(2Z)-3-(Dimethylphenylsilyl)-2-octenal
CAS No.:351194-19-9
Molecular Formula:C₁₆H₂₄OSi
Molecular Weight:260.451
Hs Code.:
DSSTox Substance ID:DTXSID801284166
Nikkaji Number:J1.573.931B,J1.812.717B

Synonyms:DTXSID801284166;(2Z)-3-(Dimethylphenylsilyl)-2-octenal;351194-19-9

Suppliers and Price of (2Z)-3-(Dimethylphenylsilyl)-2-octenal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (2Z)-3-(Dimethylphenylsilyl)-2-octenal

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:7
Exact Mass:260.159641919
Heavy Atom Count:18
Complexity:275

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCCCCC(=CC=O)[Si](C)(C)C1=CC=CC=C1
Isomeric SMILES:CCCCC/C(=C/C=O)/[Si](C)(C)C1=CC=CC=C1

Technology Process of (2Z)-3-(Dimethylphenylsilyl)-2-octenal

There total 5 articles about (2Z)-3-(Dimethylphenylsilyl)-2-octenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1846-68-0
oct-2-ynal

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 351194-19-9
(Z)-3-(dimethyl(phenyl)silyl)oct-2-enal

Guidance literature:: With picoline; copper(II) sulfate; In water; at 20 ℃; for 2h; diastereoselective reaction; Green chemistry;
DOI:10.1002/anie.201310695

Reference yield:

: 351194-43-9
(Z)-3-dimethyl(phenyl)silyl-2-octen-1-ol

: 351194-19-9
(Z)-3-(dimethyl(phenyl)silyl)oct-2-enal

: (E)-3-(dimethyl(phenyl)silyl)oct-2-enal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; In tetrahydrofuran; at -78 ℃; for 0.5h; Title compound not separated from byproducts.;
DOI:10.1021/jo025987x

Reference yield:

: 1846-68-0
oct-2-ynal

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 351194-19-9
(Z)-3-(dimethyl(phenyl)silyl)oct-2-enal

: (E)-3-(dimethyl(phenyl)silyl)oct-2-enal

Guidance literature:: With picoline; copper(II) sulfate; In water; at 20 ℃; for 2h; Reagent/catalyst; diastereoselective reaction; Green chemistry;
DOI:10.1002/anie.201310695