pentacarbonyl[bis(diphenylarsino)sulfide]chromium

Base Information

• Chemical Name: pentacarbonyl[bis(diphenylarsino)sulfide]chromium
• CAS No.: 95552-53-7
• Molecular Formula: C₂₉H₂₀As₂CrO₅S
• Molecular Weight: 682.38
• Mol file: 95552-53-7.mol

Synonyms:pentacarbonyl[bis(diphenylarsino)sulfide]chromium

Chemical Property of pentacarbonyl[bis(diphenylarsino)sulfide]chromium

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of pentacarbonyl[bis(diphenylarsino)sulfide]chromium

There total 2 articles about pentacarbonyl[bis(diphenylarsino)sulfide]chromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

bis(diphenylarsenic) sulfide (3134-95-0) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → pentacarbonyl[bis(diphenylarsino)sulfide]chromium (95552-53-7)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); suspn. of Cr(CO)6 in THF was irradiated with UV lamp for 5 h at room temp. under N2, ligand was added, stirred for 24 h at room temp.; filtered, stored at -20°C overnight;

DOI:10.1039/b005269h

Reference yield:

pentacarbonyl(dimethyloxosulfonium methylide)chromium(0) (58751-37-4) + bis(diphenylarsenic) sulfide (3134-95-0) → pentacarbonyl[bis(diphenylarsino)sulfide]chromium (95552-53-7)

Guidance literature:

In toluene; byproducts: CO, (CH3)2SO; under inert atmosphere; a mixture of Cr-complex and As-compound in toluene stirred for 24 h at 45°C; detected by IR;

upstream raw materials:

pentacarbonyl(dimethyloxosulfonium methylide)chromium⁽⁰⁾

bis(diphenylarsenic) sulfide

chromium⁽⁰⁾ hexacarbonyl