(-)-MYRTENAL TERPENE STANDARD

Base Information

• Chemical Name: (-)-MYRTENAL TERPENE STANDARD
• CAS No.: 26607-24-9
• Molecular Formula: C₁₀H₁₄O
• Molecular Weight: 150.221
• Mol file: 26607-24-9.mol

Synonyms:2-Norpinene-3-carboxaldehyde,6,6-dimethyl-, (-)- (8CI); Isomyrtenal

Chemical Property of (-)-MYRTENAL TERPENE STANDARD

Chemical Property:

• Vapor Pressure: 0.113mmHg at 25°C
• Refractive Index: n20/D 1.504
• Boiling Point: 220.499°C at 760 mmHg
• Flash Point: 80.135°C
• PSA: 17.07000
• Density: 0.988 g/mL at 20 °C(lit.)
• LogP: 2.17770
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: 23-24/25-16

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (-)-MYRTENAL TERPENE STANDARD

There total 2 articles about (-)-MYRTENAL TERPENE STANDARD which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

myrtenol (29053-01-8) → 6,6-dimethyl-3-formylbicyclo<3.1.1>hept-2-ene (80922-47-0,26607-24-9)

Guidance literature:

With oxygen; In dimethyl sulfoxide; at 20 ℃; for 6h; under 760.051 Torr; Irradiation;

DOI:10.1021/acscatal.0c05053

Reference yield:

→ 6,6-dimethyl-3-formylbicyclo<3.1.1>hept-2-ene (80922-47-0,26607-24-9)

Guidance literature:

aus d. Methylenthioverb.;

Reference yield:

6,6-dimethyl-3-formylbicyclo<3.1.1>hept-2-ene (80922-47-0,26607-24-9) + toluene-4-sulfonic acid hydrazide (1576-35-8) → C17H21N2O2S(1-)*Na(1+)

Guidance literature:

6,6-dimethyl-3-formylbicyclo<3.1.1>hept-2-ene; toluene-4-sulfonic acid hydrazide; In acetonitrile; at 90 ℃; for 6h; Inert atmosphere;

With sodium hydroxide; In acetonitrile; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1016/j.ejmech.2020.112699

upstream raw materials:

myrtenol

Refernces

• 1、 Firouzabadi, H.,Sharifi, A.. "Chromium(VI) Based Oxidants; IV. Zinc Chlorochromate Nonahydrate as an Efficient and Mild Oxidizing Agent". . p. 999 - 1002. Retrieved 2007/10/02.