(Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone

Base Information

Chemical Name:(Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone
CAS No.:1273545-12-2
Molecular Formula:C₂₀H₃₀O₆
Molecular Weight:366.455
Hs Code.:

Synonyms:(Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone

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Technology Process of (Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone

There total 3 articles about (Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1273545-05-3
(4R,5R)-(-)-4-methoxyoxalyl-5-[(1R)-menthyloxy]-γ-butyrolactone

: 106-95-6
allyl bromide

: 1273545-12-2
(Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone

Guidance literature:: With potassium carbonate; In acetone; at 20 ℃; for 24h; stereoselective reaction;
DOI:10.1080/00397911003611760

Reference yield:

: 1273545-04-2
C₁₇H₂₇NO₇

: 1273545-12-2
(Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone

Guidance literature:: Multi-step reaction with 2 steps

1: ozone; potassium hydroxide / methanol / 3 h / 0 °C

2: potassium carbonate / acetone / 24 h / 20 °C

With potassium carbonate; ozone; potassium hydroxide; In methanol; acetone; 1: Nef reaction;
DOI:10.1080/00397911003611760

Reference yield:

: [(2R,3S)-2-((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-5-oxo-tetrahydro-furan-3-yl]-aci-nitro-acetic acid ethyl ester

: 1273545-12-2
(Z)-(-)-4-(1'-allyloxy-1'-methoxycarbonylmethylidene)-(5R)-[(1R)-menthyloxy]-γ-butyrolactone

Guidance literature:: Multi-step reaction with 2 steps

1: ozone; potassium hydroxide / methanol / 3 h / 0 °C

2: potassium carbonate / acetone / 24 h / 20 °C

With potassium carbonate; ozone; potassium hydroxide; In methanol; acetone; 1: Nef reaction;
DOI:10.1080/00397911003611760