(N,N'-bis-[1-(1H-indolato-7-yl)-meth-(E)-ylidene]-benzyl-1,2-diamino)-chloro-tetrahydrofurano-chromium(III)

Base Information

• Chemical Name: (N,N'-bis-[1-(1H-indolato-7-yl)-meth-(E)-ylidene]-benzyl-1,2-diamino)-chloro-tetrahydrofurano-chromium(III)
• CAS No.: 1176887-57-2
• Molecular Formula: C₂₈H₂₄ClCrN₄O
• Molecular Weight: 519.974
• Mol file: 1176887-57-2.mol

Synonyms:(N,N'-bis-[1-(1H-indolato-7-yl)-meth-(E)-ylidene]-benzyl-1,2-diamino)-chloro-tetrahydrofurano-chromium(III)

Chemical Property of (N,N'-bis-[1-(1H-indolato-7-yl)-meth-(E)-ylidene]-benzyl-1,2-diamino)-chloro-tetrahydrofurano-chromium(III)

Chemical Property:

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MSDS Files:

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Technology Process of (N,N'-bis-[1-(1H-indolato-7-yl)-meth-(E)-ylidene]-benzyl-1,2-diamino)-chloro-tetrahydrofurano-chromium(III)

There total 1 articles about (N,N'-bis-[1-(1H-indolato-7-yl)-meth-(E)-ylidene]-benzyl-1,2-diamino)-chloro-tetrahydrofurano-chromium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N,N'-bis-[1-(1H-indol-7-yl)-methylidene]-1,2-phenylenediamine (1176887-54-9) + chromium(III) chloride (10025-73-7,16284-59-6) → (N,N'-bis-[1-(1H-indolato-7-yl)-meth-(E)-ylidene]-benzyl-1,2-diamino)-chloro-tetrahydrofurano-chromium(III) (1176887-57-2)

Guidance literature:

With n-C₄H₉Li; In tetrahydrofuran; hexane; (Ar); charging of Schlenk flask with N,N'-bis(1-(1H-undol-7-yl)-methylidene)-benzyl-1,2-diamine and THF; cooling to -80°C; addn. of soln.of n-BuLi in hexane; warming of stirred mixt. to room temp.; addn. of CrCl3; stirring for 24 h; stripping off solvents and volatile materials in vac.; trituration with dry CH2Cl2; filtration through Celite; evapn. of filtrate; drying in vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2009.04.013

upstream raw materials:

N,N'-bis-[1-(1H-indol-7-yl)-methylidene]-1,2-phenylenediamine

chromium(III) chloride