diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate

Base Information

Chemical Name:diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate
CAS No.:441785-19-9
Molecular Formula:C₂₇H₃₉O₄PSi
Molecular Weight:486.664
Hs Code.:

Synonyms:diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate

Suppliers and Price of diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate

There total 2 articles about diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1660-94-2
Tetraethyl methylenediphosphonate

: 441785-20-2
C₂₂H₂₈O₂Si

: 441785-19-9
diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 1.33333h;

Reference yield:

: 598-10-7
cyclopropane-1,1-dicarboxylic acid

: 441785-19-9
diethyl (E)-2-1-[1-({[t-butyl(diphenyl)silyl]oxy}methyl)cyclopropyl]-1-propenylphosphonate

Guidance literature:: Multi-step reaction with 6 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 17 h / 0 °C / Heating / reflux

2: sodium hydride / tetrahydrofuran / 6 h / Heating / reflux

3: tetrapropylammonium perruthennate / dichloromethane / 1 h / 20 °C

4: tetrahydrofuran / 1 h / -78 - 20 °C

5: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 1 h / 20 °C

6: n-butyllithium / tetrahydrofuran / 1.33 h / -78 - 20 °C

With lithium aluminium tetrahydride; n-butyllithium; tetrapropylammonium perruthennate; sodium hydride; 4-methylmorpholine N-oxide; In tetrahydrofuran; dichloromethane;