9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden

Base Information

• Chemical Name: 9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden
• CAS No.: 14168-84-4
• Molecular Formula: C₂₂H₁₆O₂S
• Molecular Weight: 345.426
• Mol file: 14168-84-4.mol

Synonyms:9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden

Chemical Property of 9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden

There total 4 articles about 9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

11exo-Deuterio-11endo-chlor-12anti-phenylsulfon-10,11-dihydro-5H-5,10-methano-dibenzocyclohepten → 9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden (14168-84-4)

Guidance literature:

With ethanol; sodium; In 1,4-dioxane;

DOI:10.1021/ja00978a041

Reference yield:

12anti-Phenylsulfon-10,11-dihydro-5H-5,10-methano-dibenzocycloheptenon-(11) → 9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden (14168-84-4)

Guidance literature:

Multi-step reaction with 3 steps

1: LiAlD₄

2: SOCl₂

3: Na, EtOH / dioxane

With thionyl chloride; lithium aluminium deuteride; ethanol; sodium; In 1,4-dioxane;

DOI:10.1021/ja00978a041

Reference yield:

11exo-Deuterio-12anti-phenylsulfon-10,11-dihydro-5H-5,10-methano-dibenzocycloheptenol-(11endo) → 9-Deuterio-9a-phenylsulfon-4b,9,9a,10-tetrahydro-9,10-cyclo-indeno<1.2-a>inden (14168-84-4)

Guidance literature:

Multi-step reaction with 2 steps

1: SOCl₂

2: Na, EtOH / dioxane

With thionyl chloride; ethanol; sodium; In 1,4-dioxane;

DOI:10.1021/ja00978a041

upstream raw materials:

anti-8-Phenylsulfonyldibenzobicyclo<3.2.1>octadien-exo-4-ol