methoxycarbonylmethylene triphenylarsorane

Base Information

• Chemical Name: methoxycarbonylmethylene triphenylarsorane
• CAS No.: 1529-77-7
• Molecular Formula: C₂₁H₁₉AsO₂
• Molecular Weight: 378.302
• Mol file: 1529-77-7.mol

Synonyms:methoxycarbonylmethylene triphenylarsorane

Chemical Property of methoxycarbonylmethylene triphenylarsorane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methoxycarbonylmethylene triphenylarsorane

There total 4 articles about methoxycarbonylmethylene triphenylarsorane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(methoxycarbonyl)methyl]triphenylarsonium bromide (1529-78-8) → methoxycarbonylmethylene triphenylarsorane (1529-77-7)

Guidance literature:

With potassium hydroxide;

DOI:10.1016/S0040-4020(01)99206-3

Reference yield:

triphenyl-arsane (603-32-7) → methoxycarbonylmethylene triphenylarsorane (1529-77-7)

Guidance literature:

Multi-step reaction with 2 steps

2: KOH

With potassium hydroxide;

DOI:10.1016/S0040-4020(01)99206-3

Reference yield:

triphenyl-arsane (603-32-7) + bromoacetic acid methyl ester (96-32-2) → methoxycarbonylmethylene triphenylarsorane (1529-77-7)

Guidance literature:

Multistep reaction; (i), (ii) (alkaline solution);

upstream raw materials:

[(methoxycarbonyl)methyl]triphenylarsonium bromide

triphenyl-arsane

bromoacetic acid methyl ester

Downstream raw materials:

(E)-methyl 4,5,6,8-tetra-O-benzyl-2,3-dideoxy-D-gluco-oct-2-enonate

triphenyl-arsane

Z-1-methoxycarbonylmethylene<2.2>paracyclophane

E-1-methoxycarbonylmethylene<2.2>paracyclophane