1,3A,5,7B-TETRAKIS(TRIFLUOROMETHYL)-2-PHOSPHA-6-OXA-9-OXABICYCLO[3.3.1]-NONANE-3B,7A-DIOL

Base Information

• Chemical Name: 1,3A,5,7B-TETRAKIS(TRIFLUOROMETHYL)-2-PHOSPHA-6-OXA-9-OXABICYCLO[3.3.1]-NONANE-3B,7A-DIOL
• CAS No.: 197787-23-8
• Molecular Formula: C₁₀H₇F₁₂O₄P
• Molecular Weight: 450.118
• Mol file: 197787-23-8.mol

Synonyms:1,3A,5,7B-TETRAKIS(TRIFLUOROMETHYL)-2-PHOSPHA-6-OXA-9-OXABICYCLO[3.3.1]-NONANE-3B,7A-DIOL

Chemical Property of 1,3A,5,7B-TETRAKIS(TRIFLUOROMETHYL)-2-PHOSPHA-6-OXA-9-OXABICYCLO[3.3.1]-NONANE-3B,7A-DIOL

Chemical Property:

Purity/Quality:

1,3A,5,7B-TETRAKIS(TRIFLUOROMETHYL)-2-PHOSPHA-6-OXA-9-OXABICYCLO[3.3.1]-NONANE-3B,7A-DIOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3A,5,7B-TETRAKIS(TRIFLUOROMETHYL)-2-PHOSPHA-6-OXA-9-OXABICYCLO[3.3.1]-NONANE-3B,7A-DIOL

There total 2 articles about 1,3A,5,7B-TETRAKIS(TRIFLUOROMETHYL)-2-PHOSPHA-6-OXA-9-OXABICYCLO[3.3.1]-NONANE-3B,7A-DIOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1,5,5,5-hexafluoroacetylacetone (1522-22-1) → (1SR,3SR,5RS,7RS)-1,3α,5,7β-tetrakis(trifluoromethyl)-6,9-dioxa-2-phosphabicyclo[3.3.1]nonane-3β,7α-diol (197787-23-8)

Guidance literature:

With phosphan; at 80 ℃; for 2.5h;

DOI:10.1002/cber.19971301031

Reference yield:

1,1,1,5,5,5-hexafluoroacetylacetone (1522-22-1) → (RS)-[4,4,4-trifluoro-1-hydroxy-3-oxo-1-(trifluoromethyl)butyl]phosphane + (RR,SS)-bis[4,4,4-trifluoro-1-hydroxy-3-oxo-1-(trifluoromethyl)butyl]phosphane + (1SR,3SR,5RS,7RS)-1,3α,5,7β-tetrakis(trifluoromethyl)-6,9-dioxa-2-phosphabicyclo[3.3.1]nonane-3β,7α-diol (197787-23-8)

Guidance literature:

With phosphan; for 48h; Title compound not separated from byproducts; Ambient temperature;

DOI:10.1002/cber.19971301031

upstream raw materials:

1,1,1,5,5,5-hexafluoroacetylacetone