ETHYL-4-(TRIETHOXYSILYL) BENZOATE

Base Information

• Chemical Name: ETHYL-4-(TRIETHOXYSILYL) BENZOATE
• CAS No.: 197662-64-9
• Molecular Formula: C15H24 O5 Si
• Molecular Weight: 312.438
• Mol file: 197662-64-9.mol

Synonyms:Ethyl4-(triethoxysilyl)benzoate

Chemical Property of ETHYL-4-(TRIETHOXYSILYL) BENZOATE

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.484
• Boiling Point: 334.635°C at 760 mmHg
• Flash Point: 129.813°C
• PSA: 53.99000
• Density: 1.06g/cm³
• LogP: 2.11870

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ETHYL-4-(TRIETHOXYSILYL) BENZOATE

There total 7 articles about ETHYL-4-(TRIETHOXYSILYL) BENZOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Triethoxysilane (998-30-1) + 4-iodobenzoic acid ethyl ester (51934-41-9) → benzoic acid ethyl ester (93-89-0,99341-95-4) + ethyl 1,2,4,5-tertafluoro-3-methoxybenzene (197662-64-9)

Guidance literature:

With triethylamine; acetylacetonato(1,5-cyclooctadiene)rhodium(I); In N,N-dimethyl-formamide; at 80 ℃; for 1h; Further Variations:; Solvents; Reagents; Catalysts; Product distribution;

DOI:10.1016/j.tet.2007.02.103

Reference yield: 92.0%

Triethoxysilane (998-30-1) + p-(ethoxycarbonyl)phenyl triflate (125261-30-5) → benzoic acid ethyl ester (93-89-0,99341-95-4) + ethyl 1,2,4,5-tertafluoro-3-methoxybenzene (197662-64-9)

Guidance literature:

With triethylamine; acetylacetonato(1,5-cyclooctadiene)rhodium(I); In N,N-dimethyl-formamide; at 100 ℃; for 16h; Further Variations:; Reagents; Catalysts; Product distribution;

DOI:10.1016/j.tet.2007.02.103

Reference yield: 90.0%

Triethoxysilane (998-30-1) + ethyl 4-(((nonafluorobutyl)sulfonyl)oxy)benzoate (32848-24-1) → benzoic acid ethyl ester (93-89-0,99341-95-4) + ethyl 1,2,4,5-tertafluoro-3-methoxybenzene (197662-64-9)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; triethylamine; acetylacetonato(1,5-cyclooctadiene)rhodium(I); In N,N-dimethyl-formamide; at 100 ℃; for 16h;

DOI:10.1016/j.tet.2007.02.103

upstream raw materials:

Triethoxysilane

4-iodobenzoic acid ethyl ester

Ethyl 4-bromobenzoate

ethyl 4-chlorobenzoate

Downstream raw materials:

(E)-4-(4-(ethoxycarbonyl)phenyl)but-2-en-1-ol

4-fluorobenzoic acid ethyl ester