Technology Process of C38H48O8Si
There total 8 articles about C38H48O8Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
palladium diacetate;
In
dimethyl sulfoxide;
for 72h;
DOI:10.1021/ja054750q
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: KHMDS / tetrahydrofuran / 1 h / -78 °C
1.2: tetrahydrofuran / 0.5 h / -78 °C
2.1: 167 mg / Pd(OAc)2 / dimethylsulfoxide / 72 h
With
palladium diacetate; potassium hexamethylsilazane;
In
tetrahydrofuran; dimethyl sulfoxide;
DOI:10.1021/ja054750q
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: diethyl ether; tetrahydrofuran / 1 h / 0 - 25 °C
2.1: 4-DMAP; pyridine / CH2Cl2 / 3 h / 0 °C
3.1: LDA; HMPA; TBSCl / tetrahydrofuran / 72 h / -78 - 25 °C
4.1: 180 mg / DCC; 4-DMAP / CH2Cl2 / 2 h / 0 - 25 °C
5.1: 85 percent / HF*pyridine; pyridine / tetrahydrofuran / 5 h / 0 °C
6.1: 90 percent / DMSO; oxalyl chloride; Et3N / CH2Cl2 / -78 - 0 °C
7.1: KHMDS / tetrahydrofuran / 1 h / -78 °C
7.2: tetrahydrofuran / 0.5 h / -78 °C
8.1: 167 mg / Pd(OAc)2 / dimethylsulfoxide / 72 h
With
pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; palladium diacetate; oxalyl dichloride; potassium hexamethylsilazane; pyridine hydrogenfluoride; tert-butyldimethylsilyl chloride; dimethyl sulfoxide; triethylamine; dicyclohexyl-carbodiimide; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; dichloromethane; dimethyl sulfoxide;
3.1: Ireland-Claisen rearrangement / 6.1: Swern oxidation;
DOI:10.1021/ja054750q
