o‐chlorobenzoylferrocene

Base Information

Chemical Name:o‐chlorobenzoylferrocene
CAS No.:49547-67-3
Molecular Formula:C₁₇H₁₃ClFeO
Molecular Weight:324.59
Hs Code.:

Synonyms:o‐chlorobenzoylferrocene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of o‐chlorobenzoylferrocene

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Technology Process of o‐chlorobenzoylferrocene

There total 1 articles about o‐chlorobenzoylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 102-54-5,55404-68-7
ferrocene

: 609-65-4
o-chlorobenzoyl chloride

: 49547-67-3
o‐chlorobenzoylferrocene

Guidance literature:: With aluminium chloride; In dichloromethane; ferrocene (1.0 equiv.) added to a stirred suspension of 2-chlorobenzoyl chloride (1.1 equiv.) and aluminium chloride (1.1 equiv.) in dichloromethane, stirred at room temp. overnight (16 h); washed with water, organic layer passed through a plug of alumina, washed with chloroform, washings concentrated in vacuo, crude product purified by flash column chromy. on silica gel (TLC Rf 0.30 (1:3 ether-hexane)), elem. anal.;
DOI:10.1039/b000833h

Reference yield: 90.0%

: 49547-67-3
o‐chlorobenzoylferrocene

: borane tetrahydrofuran

: 287180-12-5
(2-chlorobenzyl)ferrocene

Guidance literature:: In tetrahydrofuran; BH3*THF (1.1 equiv. of a 0.8 M solution in THF) added at room temp. to asoln. of the ferrocenyl ketone (1.0 equiv.) in THF, stirred at room tem p. overnight, water added; extracted with chloroform, dried (MgSO4), concentrated in vacuo, crude product purified by flash column chromatography on silica gel (TLC Rf 0.40 (hexane)), elem. anal.;
DOI:10.1039/b000833h

Reference yield: 87.0%

: 49547-67-3
o‐chlorobenzoylferrocene

: 591-50-4
iodobenzene

: 109-77-3
malononitrile

: C₅₅H₄₀Cl₂Fe₂N₂O₂

Guidance literature:: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium carbonate; In acetonitrile; for 16h; stereoselective reaction; Reflux; Inert atmosphere;
DOI:10.1039/c3ra43738h