(1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate

Base Information

Chemical Name:(1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate
CAS No.:112837-26-0
Molecular Formula:C₁₄H₁₈O₄S
Molecular Weight:282.361
Hs Code.:

Synonyms:(1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate

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Chemical Property of (1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate

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Technology Process of (1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate

There total 6 articles about (1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 112837-25-9
(1R,2R,6S)-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol

: 98-59-9
p-toluenesulfonyl chloride

: 112837-26-0
(1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate

Guidance literature:: In pyridine;

Reference yield:

: 18890-22-7,54423-21-1
(R)-3-methylcyclohex-2-en-1-ol

: 112837-26-0
(1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / m-chloroperbenzoic acid / CH₂Cl₂

2: 81 percent / pyridine

With 3-chloro-benzenecarboperoxoic acid; In pyridine; dichloromethane;

Reference yield:

: (R)-2-iodo-3-methylcyclohex-2-en-1-ol

: 112837-26-0
(1R,2R,3S)-2,3-epoxy-3-methylcyclohexyl tosylate

Guidance literature:: Multi-step reaction with 3 steps

1: tert.-butyl lithium / diethyl ether / 0.5 h / -78 °C / Inert atmosphere

2: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

3: triethylamine / dichloromethane / -10 °C / Inert atmosphere

With tert.-butyl lithium; triethylamine; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane;
DOI:10.1055/s-0039-1690766