[1,1-Bicyclopropyl]-2-methanol,2-(1-methylethyl)-,[1S-[1alpha(1R,2S),2bta]]-(9CI)

Base Information

Chemical Name:[1,1-Bicyclopropyl]-2-methanol,2-(1-methylethyl)-,[1S-[1alpha(1R*,2S*),2bta]]-(9CI)
CAS No.:197013-53-9
Molecular Formula:C₁₀H₁₈O
Molecular Weight:154.252
Hs Code.:
Mol file:197013-53-9.mol

Synonyms:[1,1'-Bicyclopropyl]-2-methanol,2'-(1-methylethyl)-, [1S-[1a(1'R*,2'S*),2b]]- (9CI)

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Chemical Property of [1,1-Bicyclopropyl]-2-methanol,2-(1-methylethyl)-,[1S-[1alpha(1R*,2S*),2bta]]-(9CI)

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Technology Process of [1,1-Bicyclopropyl]-2-methanol,2-(1-methylethyl)-,[1S-[1alpha(1R*,2S*),2bta]]-(9CI)

There total 3 articles about [1,1-Bicyclopropyl]-2-methanol,2-(1-methylethyl)-,[1S-[1alpha(1R*,2S*),2bta]]-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-11-6
diiodomethane

: 73540-80-4
(2E,4E)-6-methyl-2,4-heptadien-1-ol

: ((1S,2R,1'R,2'S)-2'-Isopropyl-bicyclopropyl-2-yl)-methanol

: 197013-53-9
(1SR,3RS,4RS,6SR)-1-(hydroxymethyl)-6-(2-propyl)bicyclopropane

Guidance literature:: With diethylzinc; In 1,2-dichloro-ethane; at -20 ℃; for 16h; Yield given. Yields of byproduct given;
DOI:10.1039/c39950000355

Reference yield:

: 24502-08-7
(E)-4-methylpent-2-enal

: 197013-53-9
(1SR,3RS,4RS,6SR)-1-(hydroxymethyl)-6-(2-propyl)bicyclopropane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaH / 1.) THF, 5 min, 2.) THF, -78 deg C

2: 80 percent / DIBAL-H / hexane; CH₂Cl₂ / -78 °C

3: Et₂Zn / hexane; 1,2-dichloro-ethane / 12 h / -12 °C

With diethylzinc; sodium hydride; diisobutylaluminium hydride; In hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1016/S0040-4020(96)00934-9

Reference yield:

: 73540-79-1,58679-26-8
6-methyl-hepta-2t,4t-dienoic acid methyl ester

: 197013-53-9
(1SR,3RS,4RS,6SR)-1-(hydroxymethyl)-6-(2-propyl)bicyclopropane

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / DIBAL-H / hexane; CH₂Cl₂ / -78 °C

2: Et₂Zn / hexane; 1,2-dichloro-ethane / 12 h / -12 °C

With diethylzinc; diisobutylaluminium hydride; In hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1016/S0040-4020(96)00934-9