D-myo-Inositol, 2,4,5-tris-O-(phenylmethyl)-1,6-O-(1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-ylidene-

Base Information

Chemical Name:D-myo-Inositol, 2,4,5-tris-O-(phenylmethyl)-1,6-O-(1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-ylidene-
CAS No.:196302-88-2
Molecular Formula:C37H44 O6
Molecular Weight:584.74
Hs Code.:

Synonyms:D-myo-Inositol, 2,4,5-tris-O-(phenylmethyl)-1,6-O-(1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-ylidene-

Suppliers and Price of D-myo-Inositol, 2,4,5-tris-O-(phenylmethyl)-1,6-O-(1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-ylidene-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of D-myo-Inositol, 2,4,5-tris-O-(phenylmethyl)-1,6-O-(1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-ylidene-

Chemical Property:

PSA：66.38000
LogP:6.44360

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of D-myo-Inositol, 2,4,5-tris-O-(phenylmethyl)-1,6-O-(1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-ylidene-

There total 9 articles about D-myo-Inositol, 2,4,5-tris-O-(phenylmethyl)-1,6-O-(1R,2R,4R)-1,7,7-trimethylbicyclo2.2.1hept-2-ylidene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 109280-15-1
(1R)-(+)-camphor dimethyl acetal

: 98906-30-0,104873-76-9,111466-07-0,114297-88-0,114297-91-5,114419-08-8,115184-71-9,115509-75-6,115509-76-7,118354-54-4,118354-55-5,128163-34-8,129706-80-5,136521-84-1,149713-88-2,149713-95-1
(+/-)-2,5,6-tri-O-benzyl-myo-inositol

: 196306-65-7,226889-35-6,226889-37-8,226889-38-9
C₃₇H₄₄O₆

: 196306-65-7,226889-35-6,226889-37-8,226889-38-9
C₃₇H₄₄O₆

: 196302-88-2,196306-65-7,226889-35-6,226889-37-8,226889-38-9
1D-2,4,5-tri-O-benzyl-1-O-endo,6-O-exo-(D-1',7',7'-trimethylbicyclo<2.2.1>hept-2'-ylidene)-myo-inositol

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; Title compound not separated from byproducts; Heating;
DOI:10.1039/a703044d

Reference yield: 31.0%

: 109280-15-1
(1R)-(+)-camphor dimethyl acetal

: 98906-30-0,104873-76-9,111466-07-0,114297-88-0,114297-91-5,114419-08-8,115184-71-9,115509-75-6,115509-76-7,118354-54-4,118354-55-5,128163-34-8,129706-80-5,136521-84-1,149713-88-2,149713-95-1
(+/-)-2,5,6-tri-O-benzyl-myo-inositol

: 196302-88-2,196306-65-7,226889-35-6,226889-37-8,226889-38-9
1D-2,4,5-tri-O-benzyl-1-O-endo,6-O-exo-(D-1',7',7'-trimethylbicyclo<2.2.1>hept-2'-ylidene)-myo-inositol

: 196306-65-7,226889-35-6,226889-37-8,226889-38-9
1D-2,4,5-tri-O-benzyl-1-O-exo,6-O-endo-(D-1',7',7'-trimethylbicyclo<2.2.1>hept-2'-ylidene)-myo-inositol

: 196306-65-7,226889-35-6,226889-37-8,226889-38-9
1D-2,5,6-tri-O-benzyl-3-O-exo,4-O-endo-(D-1',7',7'-trimethylbicyclo<2.2.1>hept-2'-ylidene)-myo-inositol

: 196306-65-7,226889-35-6,226889-37-8,226889-38-9
1D-2,5,6-tri-O-benzyl-3-O-endo,4-O-exo-(D-1',7',7'-trimethylbicyclo<2.2.1>hept-2'-ylidene)-myo-inositol

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; for 1.5h; Heating;

Reference yield:

: myo-inositol-1,3,5-O-orthoformate

: 196302-88-2,196306-65-7,226889-35-6,226889-37-8,226889-38-9
1D-2,4,5-tri-O-benzyl-1-O-endo,6-O-exo-(D-1',7',7'-trimethylbicyclo<2.2.1>hept-2'-ylidene)-myo-inositol

Guidance literature:: Multi-step reaction with 6 steps

1: 69 percent / NaH / dimethylformamide / 1.) 5 deg C, 10 min; r.t., 30 min, 2.) r.t., 4 h

2: 93 percent / NaH / dimethylformamide / 1.) r.t., 1 h, 2.) r.t., 1 h

3: 94 percent / DIBAL-H / hexane; CH₂Cl₂ / 1.) 0 deg C, 15 min, 2.) r.t., 7 h

4: 87 percent / NaH, imidazole / dimethylformamide / 1.) r.t., 30 min, 2.) r.t., 24 h

5: 92 percent / HCl, H₂O / methanol / 2 h / Heating

6: 31 percent / p-TsOH*H₂O / CH₂Cl₂ / 1.5 h / Heating

With 1H-imidazole; hydrogenchloride; water; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; In methanol; hexane; dichloromethane; N,N-dimethyl-formamide;