2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Base Information

Chemical Name:2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane
CAS No.:1372764-93-6
Molecular Formula:C₂₁H₂₂O₅S
Molecular Weight:386.469
Hs Code.:

Synonyms:2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Suppliers and Price of 2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

There total 6 articles about 2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 2-(S)-phenyl-(1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

: 1125-88-8
benzaldehyde dimethyl acetal

: 1372764-93-6
2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Guidance literature:: With camphor-10-sulfonic acid; In N,N-dimethyl-formamide; at 50 ℃; for 16h; under 15 Torr;
DOI:10.1021/ja3018187

Reference yield:

: 1197819-96-7
C₁₄H₁₈O₆S

: 1372764-93-6
2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Guidance literature:: Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / Inert atmosphere

2: triethylsilane; trimethylsilyl trifluoromethanesulfonate / 1,2-dichloro-ethane / Inert atmosphere

3: toluene-4-sulfonic acid / acetonitrile / 24 h / 20 °C / Inert atmosphere

With triethylsilane; trimethylsilyl trifluoromethanesulfonate; toluene-4-sulfonic acid; In 1,2-dichloro-ethane; acetonitrile;
DOI:10.1002/chem.201101889

Reference yield:

: 1197819-98-9
2-methoxy-2-(S)-phenyl-(1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

: 1372764-93-6
2-(S)-phenyl-(4,6-O-benzylidene-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Guidance literature:: Multi-step reaction with 2 steps

1: triethylsilane; trimethylsilyl trifluoromethanesulfonate / 1,2-dichloro-ethane / Inert atmosphere

2: toluene-4-sulfonic acid / acetonitrile / 24 h / 20 °C / Inert atmosphere

With triethylsilane; trimethylsilyl trifluoromethanesulfonate; toluene-4-sulfonic acid; In 1,2-dichloro-ethane; acetonitrile;
DOI:10.1002/chem.201101889