dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

Base Information

Chemical Name:dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate
CAS No.:1353118-72-5
Molecular Formula:C₃₀H₂₄O₇
Molecular Weight:496.516
Hs Code.:

Synonyms:dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

Suppliers and Price of dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 3 raw suppliers

Chemical Property of dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

Chemical Property:

Boiling Point:622.6±55.0 °C(Predicted)
Density:1.249±0.06 g/cm3(Predicted)

Purity/Quality:: 99% ^*data from raw suppliers

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Technology Process of dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

There total 1 articles about dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 118-79-6
2,4,6-tribromophenol

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 1353118-72-5
dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

Guidance literature:: With palladium diacetate; sodium carbonate; In water; N,N-dimethyl-formamide; at 60 ℃; Inert atmosphere;
DOI:10.1021/ja5123528

Reference yield: 90.0%

: 1353118-72-5
dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

: 1353118-75-8
5'-(4-carboxyphenyl)-2'-hydroxy-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid

Guidance literature:: dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate; With potassium hydroxide; In tetrahydrofuran; methanol; Reflux;

With hydrogenchloride; In water;
DOI:10.1021/ja5123528

Reference yield:

: 1353118-72-5
dimethyl 2'-hydroxy-5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate

: 1646595-32-5
5'-(4-carboxyphenyl)-2'-(prop-2-yn-1-yloxy)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / water; N,N-dimethyl-formamide / 12 h / 60 °C / Inert atmosphere

2: potassium hydroxide / tetrahydrofuran; methanol / Reflux

With potassium carbonate; potassium hydroxide; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/ja5123528