2-fluorotriphenylene

Base Information

Chemical Name:2-fluorotriphenylene
CAS No.:439-23-6
Molecular Formula:C₁₈H₁₁F
Molecular Weight:246.284
Hs Code.:

Synonyms:2-fluorotriphenylene

Suppliers and Price of 2-fluorotriphenylene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-fluorotriphenylene

Chemical Property:

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Technology Process of 2-fluorotriphenylene

There total 1 articles about 2-fluorotriphenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59142-68-6
2-bromo-4-fluorobenzaldehyde

2-fluorotriphenylene: 439-23-6
2-fluorotriphenylene

Guidance literature:: Multi-step reaction with 4 steps

1.1: magnesium; iodine / diethyl ether

1.2: 3 h / -10 - 0 °C

2.1: pyridinium chlorochromate; silica gel / dichloromethane / 2 h / 20 °C

3.1: selenium(IV) oxide; pyridine / 5 h / 90 °C / Inert atmosphere

4.1: oxygen; bis(dibenzylideneacetone)-palladium⁽⁰⁾; potassium phosphate; p-benzoquinone / N,N-dimethyl-formamide / 140 °C / Schlenk technique; Inert atmosphere

With pyridine; selenium(IV) oxide; potassium phosphate; iodine; oxygen; silica gel; magnesium; pyridinium chlorochromate; p-benzoquinone; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/acs.orglett.1c02559

Reference yield: 33.0%

2-fluorotriphenylene: 439-23-6
2-fluorotriphenylene

: 768-33-2
phenyldimethylsilyl chloride

: dimethyl(phenyl)(triphenylen-2-yl)silane

Guidance literature:: phenyldimethylsilyl chloride; With lithium; In tetrahydrofuran; at 0 ℃; for 6h; Inert atmosphere;

2-fluorotriphenylene; In tetrahydrofuran; at 0 ℃; for 20h; regioselective reaction; Inert atmosphere; Schlenk technique; Sealed tube;
DOI:10.1002/anie.201808646