(Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one

Base Information

Chemical Name:(Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one
CAS No.:128321-54-0
Molecular Formula:C₁₇H₃₀O₂Si
Molecular Weight:294.51
Hs Code.:

Synonyms:(Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one

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Chemical Property of (Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one

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Technology Process of (Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one

There total 7 articles about (Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 128321-53-9,128321-66-4
5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butynyl>-2-cyclohexen-1-one

: 128321-54-0
(Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one

Guidance literature:: With hydrogen; Pd-BaSO₄;
DOI:10.1016/S0040-4039(00)94331-4

Reference yield:

: 90933-84-9
4-(trimethylsilyl)but-2-yn-1-ol

: 128321-54-0
(Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 4 steps

1: TEA / tetrahydrofuran / 2 h / 0 deg C to r.t.

2: NaI / acetone / 2 h / 0 °C

3: 1.) lithium diisopropylamide / 1.) THF, hexanes, HMPA, -78 deg C, 20 min, 2.) -78 deg C to r.t., 12 h

4: 95 percent / hydrogen / 5 percent palladium on barium sulfate / methanol; pyridine / 6 h / 760 Torr / Ambient temperature

With TEA; hydrogen; sodium iodide; lithium diisopropyl amide; Pd-BaSO₄; In tetrahydrofuran; pyridine; methanol; acetone;
DOI:10.1021/jo00012a036

Reference yield:

: 111097-70-2
(4-Iodo-but-2-ynyl)-trimethyl-silane

: 128321-54-0
(Z)-5r,6c-Dimethyl-3-ethoxy-6-<4-(trimethylsilyl)-2-butenyl>-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) lithium diisopropylamide / 1.) THF, hexanes, HMPA, -78 deg C, 20 min, 2.) -78 deg C to r.t., 12 h

2: 95 percent / hydrogen / 5 percent palladium on barium sulfate / methanol; pyridine / 6 h / 760 Torr / Ambient temperature

With hydrogen; lithium diisopropyl amide; Pd-BaSO₄; In pyridine; methanol;
DOI:10.1021/jo00012a036