Bicyclo[4.1.0]heptan-2-one, 4-acetyl-1-methyl-, [1S-(1alpha,4beta,6alpha)]- (9CI)

Base Information

Chemical Name:Bicyclo[4.1.0]heptan-2-one, 4-acetyl-1-methyl-, [1S-(1alpha,4beta,6alpha)]- (9CI)
CAS No.:193023-36-8
Molecular Formula:C₁₀H₁₄O₂
Molecular Weight:166.22
Hs Code.:
Mol file:193023-36-8.mol

Synonyms:Bicyclo[4.1.0]heptan-2-one,4-acetyl-1-methyl-, [1S-(1a,4b,6a)]- (9CI)

Suppliers and Price of Bicyclo[4.1.0]heptan-2-one, 4-acetyl-1-methyl-, [1S-(1alpha,4beta,6alpha)]- (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[4.1.0]heptan-2-one, 4-acetyl-1-methyl-, [1S-(1alpha,4beta,6alpha)]- (9CI)

Chemical Property:

PSA：34.14000
LogP:1.58070

Purity/Quality:

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Technology Process of Bicyclo[4.1.0]heptan-2-one, 4-acetyl-1-methyl-, [1S-(1alpha,4beta,6alpha)]- (9CI)

There total 4 articles about Bicyclo[4.1.0]heptan-2-one, 4-acetyl-1-methyl-, [1S-(1alpha,4beta,6alpha)]- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 53834-63-2
(1R,4R,6R)-1-methyl-4-(2-propenyl)bicyclo<4.1.0>heptan-2-one

: 193023-36-8
(1S,4R,6R)-4-acetyl-1-methylbicyclo[4.1.0]heptan-2-one

Guidance literature:: With dimethylsulfide; sodium hydrogencarbonate; ozone; In methanol; dichloromethane; at -78 - 20 ℃;
DOI:10.1016/S0040-4020(97)00499-7

Reference yield:

: 99-48-9,1197-06-4,1197-07-5,2102-58-1,2102-59-2,5157-78-8,5503-11-7,7632-16-8,18383-51-2,22567-18-6,20307-86-2
(4R,6R)-carveol

: 193023-36-8
(1S,4R,6R)-4-acetyl-1-methylbicyclo[4.1.0]heptan-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 58 percent / Sm, HgCl₂ / tetrahydrofuran / 2.5 h / Ambient temperature

2: 88 percent / CrO₃, H₂SO₄

3: 82 percent / sodium bicarbonate, O₃, dimethylsulfide / CH₂Cl₂; methanol / -78 - 20 °C

With chromium(VI) oxide; samarium; dimethylsulfide; sulfuric acid; sodium hydrogencarbonate; ozone; mercury dichloride; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0040-4020(97)00499-7

Reference yield:

: 6485-40-1,2244-16-8
(R)-Carvone

: 193023-36-8
(1S,4R,6R)-4-acetyl-1-methylbicyclo[4.1.0]heptan-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄

2: 58 percent / Sm, HgCl₂ / tetrahydrofuran / 2.5 h / Ambient temperature

3: 88 percent / CrO₃, H₂SO₄

4: 82 percent / sodium bicarbonate, O₃, dimethylsulfide / CH₂Cl₂; methanol / -78 - 20 °C

With chromium(VI) oxide; samarium; lithium aluminium tetrahydride; dimethylsulfide; sulfuric acid; sodium hydrogencarbonate; ozone; mercury dichloride; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0040-4020(97)00499-7