methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

Base Information

Chemical Name:methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside
CAS No.:200712-56-7
Molecular Formula:C₄₅H₅₂O₁₂
Molecular Weight:784.901
Hs Code.:

Synonyms:methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

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Technology Process of methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

There total 1 articles about methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19488-48-3
methyl O-2,3,6-tri-O-benzyl-α-D-glucopyranoside

: ethyl 2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-1-thio-L-idopyranoside

: 200712-56-7
methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; In toluene; at -20 ℃; for 2h;
DOI:10.1016/S0008-6215(99)00067-1

Reference yield: 86.0%

: 200712-56-7
methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

: 162610-20-0
methyl(4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

Guidance literature:: With sodium methylate; In methanol; dichloromethane; for 1h;
DOI:10.1016/S0008-6215(99)00067-1

Reference yield:

: 200712-56-7
methyl(2-O-benzoyl-4,6-O-isopropylidene-3-O-methyl-α-L-idopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

: 200712-63-6
methyl (benzyl 4-O-levulinyl-2,3-di-O-methyl-α-L-idopyranosyluronate)-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1: 86 percent / NaOMe / methanol; CH₂Cl₂ / 1 h

2: 32.1 g / NaH / dimethylformamide / 20 °C

3: 27.5 g / CF₃COOH; water / CH₂Cl₂ / 0.42 h / 20 °C

4: triethylamine; DMAP / CH₂Cl₂ / 3 h / 50 °C

5: 38.5 g / triethylamine; DMAP / CH₂Cl₂

6: CrO₃; H₂SO₄ / acetone / 5 h / 0 °C

7: KHCO₃ / dimethylformamide / 20 °C

With chromium(VI) oxide; dmap; sulfuric acid; water; sodium methylate; sodium hydride; potassium hydrogencarbonate; triethylamine; trifluoroacetic acid; In methanol; dichloromethane; N,N-dimethyl-formamide; acetone; 1: debenzoylation / 2: Methylation / 3: Hydrolysis / 4: Etherification / 5: Acylation / 6: Oxidation / 7: Esterification;
DOI:10.1016/S0008-6215(99)00067-1