(2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

Base Information

Chemical Name:(2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one
CAS No.:808770-08-3
Molecular Formula:C₁₃H₁₆O₇
Molecular Weight:284.266
Hs Code.:

Synonyms:(2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

Suppliers and Price of (2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

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Chemical Property of (2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

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Technology Process of (2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

There total 1 articles about (2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 138-52-3
D-(-)-salicin

: 808770-08-3
(2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

: 808770-15-2
(2R,4R,5R,6S)-2-Hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-dihydro-pyran-3,3,4,5-tetraol

: 808770-11-8
(2R,3R,5S,6S)-2-Hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-3,4,4,5-tetraol

Guidance literature:: With pyranose dehydrogenase; p-benzoquinone; In water-d2; for 24h;
DOI:10.1016/j.tetlet.2004.09.149

Reference yield:

: 808770-08-3
(2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

: (2R,5S,6S)-4,4,5-Trihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-dihydro-pyran-3-one

Guidance literature:: Multi-step reaction with 2 steps

1: H₂O

2: pyranose dehydrogenase; 1,4-benzoquinone / D₂O

With pyranose dehydrogenase; water; p-benzoquinone; In water-d2;
DOI:10.1016/j.tetlet.2004.09.149

Reference yield:

: 808770-08-3
(2R,3R,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-tetrahydro-pyran-4-one

: (2R,5S,6S)-2-Hydroxymethyl-6-(2-hydroxymethyl-phenoxy)-dihydro-pyran-3,3,4,4,5-pentaol

Guidance literature:: Multi-step reaction with 3 steps

1: H₂O

2: pyranose dehydrogenase; 1,4-benzoquinone / D₂O

3: H₂O

With pyranose dehydrogenase; water; p-benzoquinone; In water-d2;
DOI:10.1016/j.tetlet.2004.09.149