2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate

Base Information

Chemical Name:2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate
CAS No.:300767-23-1
Molecular Formula:C₁₈H₂₈O₃Si
Molecular Weight:320.504
Hs Code.:

Synonyms:2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate

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Chemical Property of 2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate

Chemical Property:

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Technology Process of 2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate

There total 4 articles about 2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 108-24-7
acetic anhydride

: 300767-61-7
2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenol

: 300767-23-1
2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate

Guidance literature:: With dmap; TEA; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1248/cpb.48.1138

Reference yield:

: 1807-36-9
8-methylcoumarin

: 300767-23-1
2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate

Guidance literature:: Multi-step reaction with 3 steps

1: 42 percent / LAH / diethyl ether / 0.25 h / 0 °C

2: 73 percent / DMAP / tetrahydrofuran / 8 h / 0 °C

3: 71 percent / DMAP; TEA / CH₂Cl₂ / 1 h / 20 °C

With dmap; lithium aluminium tetrahydride; TEA; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1248/cpb.48.1138

Reference yield:

: 95-48-7,77504-84-8
ortho-cresol

: 300767-23-1
2-[(Z)-3-{[1-(tert-butyl)-1,1-dimethyl-silanyl]oxy}-1-propenyl]-6-methylphenyl acetate

Guidance literature:: Multi-step reaction with 4 steps

1: 40 percent / methanesulfonic acid / 4 h / 85 - 90 °C

2: 42 percent / LAH / diethyl ether / 0.25 h / 0 °C

3: 73 percent / DMAP / tetrahydrofuran / 8 h / 0 °C

4: 71 percent / DMAP; TEA / CH₂Cl₂ / 1 h / 20 °C

With dmap; lithium aluminium tetrahydride; methanesulfonic acid; TEA; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1248/cpb.48.1138