C₂₇H₃₈O₅Si

Base Information

• Chemical Name: C₂₇H₃₈O₅Si
• CAS No.: 298691-02-8
• Molecular Formula: C₂₇H₃₈O₅Si
• Molecular Weight: 470.681
• Mol file: 298691-02-8.mol

Synonyms:C₂₇H₃₈O₅Si

Chemical Property of C₂₇H₃₈O₅Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇H₃₈O₅Si

There total 5 articles about C₂₇H₃₈O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.5%

C27H36O5Si → C27H38O5Si (298691-02-8)

Guidance literature:

With palladium on carbon; hydrogen; In ethanol; at 20 ℃;

DOI:10.1016/j.bmcl.2011.02.021

Reference yield:

1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-3,3-bis-ethylsulfanyl-propan-1-ol (67320-20-1,83692-41-5,94292-91-8,64722-95-8) → C27H38O5Si (298691-02-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 1H-imidazole / dichloromethane / 20 °C

2: periodic acid / tetrahydrofuran; diethyl ether / 0 °C

3: tetrahydrofuran / 20 °C

4: palladium on carbon; hydrogen / ethanol / 20 °C

With 1H-imidazole; palladium on carbon; hydrogen; periodic acid; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane;

DOI:10.1016/j.bmcl.2011.02.021

Reference yield:

2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose (93292-42-3) → C27H38O5Si (298691-02-8)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran / 20 °C

2: palladium on carbon; hydrogen / ethanol / 20 °C

With palladium on carbon; hydrogen; In tetrahydrofuran; ethanol;

DOI:10.1016/j.bmcl.2011.02.021

upstream raw materials:

1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-3,3-bis-ethylsulfanyl-propan-1-ol

2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose

2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal

tert-butylchlorodiphenylsilane

Downstream raw materials:

C₃₁H₄₀O₄Si

C₃₇H₄₉F₃O₃Si

C₃₆H₄₇F₃O₃Si

C₃₂H₄₄O₅Si

Refernces