2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene

Base Information

• Chemical Name: 2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene
• CAS No.: 950566-17-3
• Molecular Formula: C₁₉H₁₄O₂S₄
• Molecular Weight: 402.583
• Mol file: 950566-17-3.mol

Synonyms:2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene

Chemical Property of 2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene

There total 2 articles about 2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

2-methylseleno-5-(p-acetoxyphenyl)-4-methyl-1,3-dithiolium trifluoromethanesulfonate + C25H20PS2(1+)*F6P(1-) (117156-71-5) → 2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene (950566-17-3)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; for 4h;

DOI:10.3390/11100776

Reference yield: 31.0%

benzo[d][1,3]dithiol-2-yltriphenylphosphonium tetrafluoroborate + C12H11O2S2(1+)*F6P(1-) → dibenzotetrathiafulvalene (24648-13-3) + di-(p-acetoxyphenyl)-dimethyl tetrathiafulvalene + 2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene (950566-17-3)

Guidance literature:

With triethylamine; In acetonitrile; at 20 ℃;

DOI:10.1039/B308514G

Reference yield: 80.0%

2-(4-acetoxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene (950566-17-3) → 2-(4-hydroxyphenyl)-3-methyl-6,7-(buta-1,3-diene-1,4-diyl)tetrathiafulvalene

Guidance literature:

With hydrazine hydrate; In methanol; at 20 ℃; for 4h;

DOI:10.3390/11100776

upstream raw materials:

C₂₅H₂₀PS₂⁽¹⁺⁾*F₆P^(1-)