3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate)

Base Information

• Chemical Name: 3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate)
• CAS No.: 1393330-16-9
• Molecular Formula: C₃₇H₃₆O₇
• Molecular Weight: 592.689
• Mol file: 1393330-16-9.mol

Synonyms:3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate)

Chemical Property of 3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate)

There total 1 articles about 3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C16H18O7 (1393330-17-0) + benzyl chloride (100-44-7) → 3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate) (1393330-16-9)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; at 20 ℃; for 4h; Inert atmosphere;

DOI:10.1007/s10719-012-9400-7

Reference yield: 93.0%

methyl 2,3,4-tri-O-benzoylglucopyranoside (34234-44-1) + 3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate) (1393330-16-9) → methyl-2,3,4-tri-O-benzoyl-6-O-(2-O-benzoyl-3,4,6-tri-O-benzyl α-D-mannopyranosyl)-α-D-glucopyranoside

Guidance literature:

With C₂₇H₄₇AuN₃Si₃⁽¹⁺⁾*F₆Sb^(1-); In dichloromethane; at 25 ℃; for 0.25h; Molecular sieve; Inert atmosphere;

DOI:10.1039/d0cc03156a

Reference yield: 86.0%

methyl 2,3,4-tri-O-benzoylglucopyranoside (34234-44-1) + 3,4,6-tri-O-benzyl-β-D-mannopyranose-1,2-(prop-2-ynyl orthobenzoate) (1393330-16-9) → methyl-2,3,4-tri-O-benzoyl-6-O-(2-O-benzoyl-3,4,6-tri-O-benzyl α-D-mannopyranosyl)-α-D-glucopyranoside + C37H36O7

Guidance literature:

With C₂₇H₄₇AuGeN₃Si₂⁽¹⁺⁾*F₆Sb^(1-); In dichloromethane; at 25 ℃; for 0.25h; Reagent/catalyst; Molecular sieve; Inert atmosphere;

DOI:10.1039/d0cc03156a

upstream raw materials:

C₁₆H₁₈O₇

benzyl chloride