benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

Base Information

Chemical Name:benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate
CAS No.:1310457-15-8
Molecular Formula:C₂₀H₂₅NO₃
Molecular Weight:327.423
Hs Code.:

Synonyms:benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

Suppliers and Price of benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

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Technology Process of benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

There total 2 articles about benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₉H₂₁NO₃

: 1310457-15-8
benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: aluminum oxide / ethyl acetate / 20 h / 20 °C / Inert atmosphere

2.1: copper(l) iodide / tetrahydrofuran; diethyl ether / 0.92 h / -78 - 20 °C / Inert atmosphere

2.2: 3 h / -78 °C / Inert atmosphere

With aluminum oxide; copper(l) iodide; In tetrahydrofuran; diethyl ether; ethyl acetate;
DOI:10.1021/jo200745n

Reference yield:

: benzyl (3S,4aS,8aS)-3-ethenyl-5-hydroxy-3,4,4a,5,6,8ahexahydroquinoline-1(2H)-carboxylate

: 1310457-15-8
benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: Dess-Martin periodane / dichloromethane / 20 °C / Inert atmosphere

2.1: aluminum oxide / ethyl acetate / 20 h / 20 °C / Inert atmosphere

3.1: copper(l) iodide / tetrahydrofuran; diethyl ether / 0.92 h / -78 - 20 °C / Inert atmosphere

3.2: 3 h / -78 °C / Inert atmosphere

With aluminum oxide; copper(l) iodide; Dess-Martin periodane; In tetrahydrofuran; diethyl ether; dichloromethane; ethyl acetate;
DOI:10.1021/jo200745n

Reference yield: 78.0%

: 1310457-15-8
benzyl (3S,4aS,7S,8aS)-3-ethenyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

: 1310457-11-4
benzyl (3R,4aS,7S,8aS)-3-acetyl-7-methyl-5-oxooctahydroquinoline-1(2H)-carboxylate

Guidance literature:: With oxygen; copper dichloride; palladium dichloride; In tetrahydrofuran; water; at 20 ℃; for 24h;
DOI:10.1021/jo200745n