phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine

Base Information

• Chemical Name: phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine
• CAS No.: 1312947-06-0
• Molecular Formula: C₂₀H₁₈NOPS
• Molecular Weight: 351.409
• Mol file: 1312947-06-0.mol

Synonyms:phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine

Chemical Property of phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine

There total 3 articles about phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-sulfide (1259405-60-1) + phenethylamine (64-04-0) → phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine (1312947-06-0)

Guidance literature:

With chloroform; triethylamine; In tetrachloromethane; at 5 - 10 ℃;

DOI:10.3987/COM-10-12124

Reference yield:

p-chlorodibenzo[c.e][1,2]oxaphosphorine (22749-43-5) → phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine (1312947-06-0)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogen sulfide; sodium hydroxide / water; toluene / 20 °C

2: chloroform; triethylamine / tetrachloromethane / 5 - 10 °C

With chloroform; hydrogen sulfide; triethylamine; sodium hydroxide; In tetrachloromethane; water; toluene; 2: Atherton-Todd reaction;

DOI:10.3987/COM-10-12124

Reference yield:

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (35948-25-5) → phenethyl-(10-thioxo-10H-9-oxa-10λ5-phosphaphenanthren-10-yl)amine (1312947-06-0)

Guidance literature:

Multi-step reaction with 2 steps

1: tetraphosphorus decasulfide / toluene / 17 h / 40 - 55 °C / Inert atmosphere

2: chloroform; triethylamine / tetrachloromethane / 5 - 10 °C

With tetraphosphorus decasulfide; chloroform; triethylamine; In tetrachloromethane; toluene; 2: Atherton-Todd reaction;

DOI:10.3987/COM-10-12124

upstream raw materials:

p-chlorodibenzo[c.e][1,2]oxaphosphorine

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-sulfide

phenethylamine

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide