6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

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Chemical Name:6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid
CAS No.:256331-34-7
Molecular Formula:C₂₉H₃₆O₁₆S
Molecular Weight:672.661
Hs Code.:

6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

Synonyms:6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

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Chemical Property of 6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

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Technology Process of 6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

There total 7 articles about 6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 256331-33-6
Methanesulfonic acid (1S,2S,3R)-1,2-bis-ethoxycarbonyloxymethyl-3-(6-formyl-benzo[1,3]dioxol-5-yl)-3-(3,4,5-trimethoxy-phenyl)-propyl ester

: 256331-34-7
6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

Guidance literature:: With sodium chlorite; 2-methyl-but-2-ene; In tert-butyl alcohol; pH=4;
DOI:10.1016/S0040-4039(99)01932-2

Reference yield:

: Carbonic acid (5R,6R)-7-ethoxycarbonyloxymethyl-5-(3,4,5-trimethoxy-phenyl)-5,6-dihydro-naphtho[2,3-d][1,3]dioxol-6-ylmethyl ester ethyl ester

: 256331-34-7
6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

Guidance literature:: Multi-step reaction with 5 steps

1: O₃; Me₂S / methanol; CHCl₃ / -78 °C

2: 24 percent / BH₃ / tetrahydrofuran / 20 °C

3: 84 percent / MnO₂ / acetonitrile / 20 °C

4: 84 percent / Et₃N / methanol / 20 °C

5: 100 percent / NaClO₂; 2-methyl-2-butene / 2-methyl-propan-2-ol / pH 4

With manganese(IV) oxide; sodium chlorite; 2-methyl-but-2-ene; dimethylsulfide; borane; ozone; triethylamine; In tetrahydrofuran; methanol; chloroform; acetonitrile; tert-butyl alcohol; 1: Oxidation / 2: Reduction / 3: Oxidation / 4: Esterification / 5: Oxidation;
DOI:10.1016/S0040-4039(99)01932-2

Reference yield:

: 256331-29-0
Carbonic acid (3S,4R)-3-ethoxycarbonyloxymethyl-4-(6-formyl-benzo[1,3]dioxol-5-yl)-2-oxo-4-(3,4,5-trimethoxy-phenyl)-butyl ester ethyl ester

: 256331-34-7
6-[(1R,2S,3S)-4-Ethoxycarbonyloxy-2-ethoxycarbonyloxymethyl-3-methanesulfonyloxy-1-(3,4,5-trimethoxy-phenyl)-butyl]-benzo[1,3]dioxole-5-carboxylic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 24 percent / BH₃ / tetrahydrofuran / 20 °C

2: 84 percent / MnO₂ / acetonitrile / 20 °C

3: 84 percent / Et₃N / methanol / 20 °C

4: 100 percent / NaClO₂; 2-methyl-2-butene / 2-methyl-propan-2-ol / pH 4

With manganese(IV) oxide; sodium chlorite; 2-methyl-but-2-ene; borane; triethylamine; In tetrahydrofuran; methanol; acetonitrile; tert-butyl alcohol; 1: Reduction / 2: Oxidation / 3: Esterification / 4: Oxidation;
DOI:10.1016/S0040-4039(99)01932-2