(+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane

Base Information

Chemical Name:(+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane
CAS No.:904881-36-3
Molecular Formula:C₂₇H₃₈O₂Si
Molecular Weight:422.683
Hs Code.:

Synonyms:(+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane

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Chemical Property of (+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane

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Technology Process of (+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane

There total 3 articles about (+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 904881-28-3
(+)-(1R)-2-butyl-3-methyl-cyclohex-2-enol

: 904881-36-3
(+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: t-BuOOH / VO(acac)2 / benzene / 5 - 20 °C

2: imidazole / dimethylformamide / 0 - 20 °C

With 1H-imidazole; tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In N,N-dimethyl-formamide; benzene;
DOI:10.1021/jo0604080

Reference yield:

: 13679-29-3
2-butyl-3-methyl-2-cyclohexenone

: 904881-36-3
(+)-(1R,2R,6S)-(1-butyl-6-methyl-7-oxa-bicyclo[4.1.0]hept-2-yloxy)-tert-butyldiphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: BH₃*SMe₂; (S)-1-Me-3,3-Ph₂-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole / tetrahydrofuran; toluene / 1 h / 0 °C

2: t-BuOOH / VO(acac)2 / benzene / 5 - 20 °C

3: imidazole / dimethylformamide / 0 - 20 °C

With 1H-imidazole; tert.-butylhydroperoxide; dimethylsulfide borane complex; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; bis(acetylacetonate)oxovanadium; In tetrahydrofuran; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/jo0604080